Intermolecular Oxidative C-N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp(2) and Benzylic sp(3) C-H Bond Imidation

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dc.contributor.authorKim, Hyun-Jinko
dc.contributor.authorKim, Ji-Yuko
dc.contributor.authorCho, Seung-Hwanko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2013-03-09T07:23:04Z-
dc.date.available2013-03-09T07:23:04Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2011-10-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.41, pp.16382 - 16385-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/95721-
dc.description.abstractA new synthetic approach toward intermolecular oxidative C-N bond formation of arenes has been developed under transition-metal-free conditions. Complete control of chemoselectivity between aryl sp(2) and benzylic sp(3) C-H bond imidation was achieved by the choice of nitrogen sources, representatively being phthalimide and dibenzenesulfonimide, respectively.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectELECTROPHILIC AROMATIC-SUBSTITUTION-
dc.subjectHYPERVALENT IODINE COMPOUNDS-
dc.subjectCATALYZED DIRECT AMINATION-
dc.subjectNITRENIUM IONS-
dc.subjectHETEROCYCLIC-COMPOUNDS-
dc.subjectAMBIENT-TEMPERATURE-
dc.subjectACYLNITRENIUM IONS-
dc.subjectSINGLE-ELECTRON-
dc.subjectAMIDATION-
dc.subjectROUTE-
dc.titleIntermolecular Oxidative C-N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp(2) and Benzylic sp(3) C-H Bond Imidation-
dc.typeArticle-
dc.identifier.wosid000295997500017-
dc.identifier.scopusid2-s2.0-80054764821-
dc.type.rimsART-
dc.citation.volume133-
dc.citation.issue41-
dc.citation.beginningpage16382-
dc.citation.endingpage16385-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorChang, Suk-Bok-
dc.contributor.nonIdAuthorKim, Ji-Yu-
dc.contributor.nonIdAuthorCho, Seung-Hwan-
dc.type.journalArticleArticle-
dc.subject.keywordPlusELECTROPHILIC AROMATIC-SUBSTITUTION-
dc.subject.keywordPlusHYPERVALENT IODINE COMPOUNDS-
dc.subject.keywordPlusCATALYZED DIRECT AMINATION-
dc.subject.keywordPlusNITRENIUM IONS-
dc.subject.keywordPlusHETEROCYCLIC-COMPOUNDS-
dc.subject.keywordPlusAMBIENT-TEMPERATURE-
dc.subject.keywordPlusACYLNITRENIUM IONS-
dc.subject.keywordPlusSINGLE-ELECTRON-
dc.subject.keywordPlusAMIDATION-
dc.subject.keywordPlusROUTE-
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