DC Field | Value | Language |
---|---|---|
dc.contributor.author | Spruell, Jason M. | ko |
dc.contributor.author | Paxton, Walter F. | ko |
dc.contributor.author | Olsen, John-Carl | ko |
dc.contributor.author | Benitez, Diego | ko |
dc.contributor.author | Tkatchouk, Ekaterina | ko |
dc.contributor.author | Stern, Charlotte L. | ko |
dc.contributor.author | Trabolsi, Ali | ko |
dc.contributor.author | Friedman, Douglas C. | ko |
dc.contributor.author | Goddard, William A., III | ko |
dc.contributor.author | Stoddart, James Fraser | ko |
dc.date.accessioned | 2013-03-08T22:03:13Z | - |
dc.date.available | 2013-03-08T22:03:13Z | - |
dc.date.created | 2012-03-14 | - |
dc.date.created | 2012-03-14 | - |
dc.date.issued | 2009-08 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.32, pp.11571 - 11580 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/94429 | - |
dc.description.abstract | The preparation, characterization, and switching mechanism of a unique single-station mechanically switchable hetero[2]catenane are reported. The facile synthesis utilizing a "threading-followed-by-clipping" protocol features Cu(2+)-catalyzed Eglinton coupling as a mild and efficient route to the tetrathiafulvalene-based catenane in high yield. The resulting mechanically interlocked molecule operates as a perfect molecular switch, most readily described as a "push-button" switch, whereby two discrete and fully occupied translational states are toggled electrochemically at incredibly high rates. This mechanical switching was probed using a wide variety of experimental techniques as well as quantum-mechanical investigations. The fundamental distinctions between this single-station [2]catenane and other more traditional bi- and multistation molecular switches are significant. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TEMPLATE-DIRECTED SYNTHESIS | - |
dc.subject | DENSITY FUNCTIONALS | - |
dc.subject | INTERLOCKED MOLECULES | - |
dc.subject | CLICK CHEMISTRY | - |
dc.subject | ROTAXANES | - |
dc.subject | ELECTRONICS | - |
dc.subject | CYCLOBIS(PARAQUAT-P-PHENYLENE) | - |
dc.subject | TETRATHIAFULVALENE | - |
dc.subject | CATENANES | - |
dc.subject | MACHINES | - |
dc.title | A Push-Button Molecular Switch | - |
dc.type | Article | - |
dc.identifier.wosid | 000269379200062 | - |
dc.identifier.scopusid | 2-s2.0-68849102764 | - |
dc.type.rims | ART | - |
dc.citation.volume | 131 | - |
dc.citation.issue | 32 | - |
dc.citation.beginningpage | 11571 | - |
dc.citation.endingpage | 11580 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja904104c | - |
dc.contributor.nonIdAuthor | Spruell, Jason M. | - |
dc.contributor.nonIdAuthor | Paxton, Walter F. | - |
dc.contributor.nonIdAuthor | Olsen, John-Carl | - |
dc.contributor.nonIdAuthor | Benitez, Diego | - |
dc.contributor.nonIdAuthor | Tkatchouk, Ekaterina | - |
dc.contributor.nonIdAuthor | Stern, Charlotte L. | - |
dc.contributor.nonIdAuthor | Trabolsi, Ali | - |
dc.contributor.nonIdAuthor | Friedman, Douglas C. | - |
dc.contributor.nonIdAuthor | Goddard, William A., III | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TEMPLATE-DIRECTED SYNTHESIS | - |
dc.subject.keywordPlus | DENSITY FUNCTIONALS | - |
dc.subject.keywordPlus | INTERLOCKED MOLECULES | - |
dc.subject.keywordPlus | CLICK CHEMISTRY | - |
dc.subject.keywordPlus | ROTAXANES | - |
dc.subject.keywordPlus | ELECTRONICS | - |
dc.subject.keywordPlus | CYCLOBIS(PARAQUAT-P-PHENYLENE) | - |
dc.subject.keywordPlus | TETRATHIAFULVALENE | - |
dc.subject.keywordPlus | CATENANES | - |
dc.subject.keywordPlus | MACHINES | - |
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