DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhao, Yan-Li | ko |
dc.contributor.author | Benitez, Diego | ko |
dc.contributor.author | Yoon, Il | ko |
dc.contributor.author | Stoddart, James Fraser | ko |
dc.date.accessioned | 2013-03-08T20:19:26Z | - |
dc.date.available | 2013-03-08T20:19:26Z | - |
dc.date.created | 2012-03-15 | - |
dc.date.created | 2012-03-15 | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | CHEMISTRY-AN ASIAN JOURNAL, v.4, no.3, pp.446 - 456 | - |
dc.identifier.issn | 1861-4728 | - |
dc.identifier.uri | http://hdl.handle.net/10203/94188 | - |
dc.description.abstract | The 1:1 complexation of beta-cyclodextrin (P-CD) with structurally similar bipyridine guests which lead to the formation of six inclusion complexes (1-6) of P-CD with 4,4'-vinylenedipyridine, 2,2'-vinylenedipyridine, 1-(2-pyridyl)-2-(4-pyridyl)ethylene, 4.4'-ethylene-dipyridine, 4.4'-dithiodipyridine, and 2,2'-dithiodipyridine has been investigated comprehensively by X-ray crystallography in the solid state and by (1)HNMR spectroscopy and microcalorimetric titration in aqueous solution. The complex formation constants (K,) for the stoichiometric 1:1 host-guest inclusion complexation of beta-CD with the bipyridine derivatives were determined in aqueous solution by microcalorimetry and the host-guest inclusion geometries of the complexes were deduced from (1)H ROESY NNIR spectroscopy. It transpires that the guest bipyridine molecules are included in the P-CD cavity with a range of different inclusion geometries. In the solid state, the crystal superstructures for the P-CD complexes 11, 4, and 5 are characterized by the triclinic crystal system (space group PI) commensurate with AAAA type supramolecular aggregation. By contrast, the P-CD complexes 2, 3, and 6 display either monoclinic (space group P2(1)) or orthorhombic (space group C222(1)) crystal systems, characteristic of ABAB type supramolecular aggregation. The results demonstrate that the relative locations of the nitrogen atom positions and the bridge-bond links between the two pyridine rings in these bipyridine guests, not only lead to distinct crystal systems and space groups, but also to different binding geometries and thermodynamical parameters on complexation of the bipyridines with beta-CD. The knowledge obtained from this research improves our understanding of the molecular recognition and self-assembly processes exhibited by beta-CD, both in the solid state and in aqueous solution. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | AMINO-ACID DERIVATIVES | - |
dc.subject | X-RAY-STRUCTURE | - |
dc.subject | NONOPIATE ANALGESIC DRUGS | - |
dc.subject | ACETYL-L-PHENYLALANINE | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | ASSEMBLY BEHAVIOR | - |
dc.subject | (Z)-TETRADEC-7-ENOIC ACID | - |
dc.subject | ROCURONIUM COMPLEXES | - |
dc.subject | CHIRAL RECOGNITION | - |
dc.subject | ALPHA-CYCLODEXTRIN | - |
dc.title | Inclusion Behavior of beta-Cyclodextrin with Bipyridine Molecules: Factors Governing Host-Guest Inclusion Geometries | - |
dc.type | Article | - |
dc.identifier.wosid | 000264168100012 | - |
dc.identifier.scopusid | 2-s2.0-62749172896 | - |
dc.type.rims | ART | - |
dc.citation.volume | 4 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 446 | - |
dc.citation.endingpage | 456 | - |
dc.citation.publicationname | CHEMISTRY-AN ASIAN JOURNAL | - |
dc.identifier.doi | 10.1002/asia.200800373 | - |
dc.contributor.nonIdAuthor | Zhao, Yan-Li | - |
dc.contributor.nonIdAuthor | Benitez, Diego | - |
dc.contributor.nonIdAuthor | Yoon, Il | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | crystal structures | - |
dc.subject.keywordAuthor | cyclodextrins | - |
dc.subject.keywordAuthor | host-guest systems | - |
dc.subject.keywordAuthor | inclusion compounds | - |
dc.subject.keywordAuthor | NMR spectroscopy | - |
dc.subject.keywordPlus | AMINO-ACID DERIVATIVES | - |
dc.subject.keywordPlus | X-RAY-STRUCTURE | - |
dc.subject.keywordPlus | NONOPIATE ANALGESIC DRUGS | - |
dc.subject.keywordPlus | ACETYL-L-PHENYLALANINE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | ASSEMBLY BEHAVIOR | - |
dc.subject.keywordPlus | (Z)-TETRADEC-7-ENOIC ACID | - |
dc.subject.keywordPlus | ROCURONIUM COMPLEXES | - |
dc.subject.keywordPlus | CHIRAL RECOGNITION | - |
dc.subject.keywordPlus | ALPHA-CYCLODEXTRIN | - |
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