DC Field | Value | Language |
---|---|---|
dc.contributor.author | Coskun, Ali | ko |
dc.contributor.author | Saha, Sourav | ko |
dc.contributor.author | Aprahamian, Ivan | ko |
dc.contributor.author | Stoddart, J. Fraser | ko |
dc.date.accessioned | 2013-03-08T08:21:38Z | - |
dc.date.available | 2013-03-08T08:21:38Z | - |
dc.date.created | 2012-05-29 | - |
dc.date.created | 2012-05-29 | - |
dc.date.issued | 2008-08 | - |
dc.identifier.citation | ORGANIC LETTERS, v.10, no.15, pp.3187 - 3190 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10203/92586 | - |
dc.description.abstract | A [2]catenane, composed of a pi-electron-rich bis-1,5-dioxynaphthalene[38]crown10 (BDNP38C10) ring, mechanically interlocked with a large macrocycle containing two disubstituted tetraarylmethane "speed bumps" and two different pi-electron-deficient units-namely, naphthalene dimide (Npl) and bipyridinium (Blpy(2+)) units-has been synthesized from a [2]rotaxane, containing the former recognition unit, after performing two sequential Cu(l)-catalyzed azide-alkyne cycloadditions with a linker containing the latter recognition unit. The product, which exists as a single co-conformer, wherein the BDNP38C10 ring encircles the Npl unit, undergoes equilibration to give approximately equal amounts of the other co-conformer in which the BDNP38C10 ring encircles the Blpy(2+) unit. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TUNNEL-JUNCTION DEVICES | - |
dc.subject | TEMPLATED SYNTHESIS | - |
dc.subject | TETRATHIAFULVALENE UNIT | - |
dc.subject | MOLECULAR ELECTRONICS | - |
dc.subject | TERMINAL ALKYNES | - |
dc.subject | CLICK CHEMISTRY | - |
dc.subject | ROTAXANES | - |
dc.subject | SWITCH | - |
dc.subject | PSEUDOROTAXANE | - |
dc.subject | MACHINES | - |
dc.title | A reverse donor-acceptor bistable [2]Catenane | - |
dc.type | Article | - |
dc.identifier.wosid | 000257955100005 | - |
dc.identifier.scopusid | 2-s2.0-58149192565 | - |
dc.type.rims | ART | - |
dc.citation.volume | 10 | - |
dc.citation.issue | 15 | - |
dc.citation.beginningpage | 3187 | - |
dc.citation.endingpage | 3190 | - |
dc.citation.publicationname | ORGANIC LETTERS | - |
dc.identifier.doi | 10.1021/ol80093lz | - |
dc.contributor.localauthor | Coskun, Ali | - |
dc.contributor.nonIdAuthor | Saha, Sourav | - |
dc.contributor.nonIdAuthor | Aprahamian, Ivan | - |
dc.contributor.nonIdAuthor | Stoddart, J. Fraser | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TUNNEL-JUNCTION DEVICES | - |
dc.subject.keywordPlus | TEMPLATED SYNTHESIS | - |
dc.subject.keywordPlus | TETRATHIAFULVALENE UNIT | - |
dc.subject.keywordPlus | MOLECULAR ELECTRONICS | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | CLICK CHEMISTRY | - |
dc.subject.keywordPlus | ROTAXANES | - |
dc.subject.keywordPlus | SWITCH | - |
dc.subject.keywordPlus | PSEUDOROTAXANE | - |
dc.subject.keywordPlus | MACHINES | - |
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