Localized corrosion of Alloy C22 nuclear waste canister material under limiting conditions

Abstract

Localized corrosion behavior of Alloy C22 in simulated Yucca Mountain (YM) repository environments was studied at the highest achievable but realistic temperatures under boiling and dripping scenarios. Temperatures measured in concentrated boiling solutions of KCl and NaNO3 were found to be stable at 140 degrees C, although transient boiling before dryout was observed at temperatures as high as 160 degrees C, as the electrolyte became progressively more concentrated. Experiments that simulated a dripping scenario with simulated J13 well water confirmed the existence of concentrated solutions stable at 142 +/- 3 degrees C under controlled drip conditions leading to pit initiation in Alloy C22 after only a few hours. The polarization experiments conducted at 140 degrees C in a solution with 0.5 mol L-1 chloride concentration showed that the critical potential for localized corrosion was 250 mV (versus Ag/AgCl). Potentiostatic tests confirmed that active metal dissolution occurred only in the crevice region at this potential. The crevice corrosion of Alloy C22 required an incubation time to develop a critical crevice solution, and it was triggered by severe local chemistry (enrichment of Cl- and H+) aided by the high temperature. (c) 2006 Elsevier B.V. All rights reserved.