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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Facile Barton-McCombie deoxygenation of alcohols with tetrabutylammonium peroxydisulfate and formate ion

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dc.contributor.authorPark, HSko
dc.contributor.authorLee, Hee Yoonko
dc.contributor.authorKim, Yong Haeko
dc.date.accessioned2013-03-07T19:02:57Z-
dc.date.available2013-03-07T19:02:57Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-07-
dc.identifier.citationORGANIC LETTERS, v.7, no.15, pp.3187 - 3190-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/91009-
dc.description.abstractA new method for efficient radical deoxygenation of alcohols is described for preparing bulk chemicals avoiding scale-up problems. Treatment of various thiocarbonyl derivatives with (Bu4N)(2)S2O8 and HCO2Na in DMF afforded the corresponding deoxygenated products in excellent yields. The deoxygenation appears to be initiated by the transfer of a single electron to thiocarbonyl derivatives from CO2.- rather than from SO4-.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMORPHINE-THEBAINE GROUP-
dc.subjectMOLECULAR REARRANGEMENTS-
dc.subjectRADICAL REACTIONS-
dc.subjectTHIOCARBONYL DERIVATIVES-
dc.subjectSECONDARY ALCOHOLS-
dc.subjectALKYL-HALIDES-
dc.subjectANALGESICS-
dc.subjectXANTHATES-
dc.subject6,14-ENDO-ETHENOTETRAHYDROTHEBAINE-
dc.subjectERYTHROMYCINS-
dc.titleFacile Barton-McCombie deoxygenation of alcohols with tetrabutylammonium peroxydisulfate and formate ion-
dc.typeArticle-
dc.identifier.wosid000230567200014-
dc.identifier.scopusid2-s2.0-23044500774-
dc.type.rimsART-
dc.citation.volume7-
dc.citation.issue15-
dc.citation.beginningpage3187-
dc.citation.endingpage3190-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol050886h-
dc.contributor.localauthorLee, Hee Yoon-
dc.contributor.nonIdAuthorPark, HS-
dc.type.journalArticleArticle-
dc.subject.keywordPlusMORPHINE-THEBAINE GROUP-
dc.subject.keywordPlusMOLECULAR REARRANGEMENTS-
dc.subject.keywordPlusRADICAL REACTIONS-
dc.subject.keywordPlusTHIOCARBONYL DERIVATIVES-
dc.subject.keywordPlusSECONDARY ALCOHOLS-
dc.subject.keywordPlusALKYL-HALIDES-
dc.subject.keywordPlusANALGESICS-
dc.subject.keywordPlusXANTHATES-
dc.subject.keywordPlus6,14-ENDO-ETHENOTETRAHYDROTHEBAINE-
dc.subject.keywordPlusERYTHROMYCINS-
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