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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Stereofacial control in asymmetric cyanosilylation of aldehydes catalyzed by novel S-proline-derived titanium complexes

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dc.contributor.authorKim, YBko
dc.contributor.authorKim, MKko
dc.contributor.authorKang, SungHoko
dc.contributor.authorKim, Yong Haeko
dc.date.accessioned2013-03-07T19:00:19Z-
dc.date.available2013-03-07T19:00:19Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-08-
dc.identifier.citationSYNLETT, v.13, pp.1995 - 1998-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/10203/91002-
dc.description.abstractAsymmetric cyanosilylation of aryl aldehydes has been achieved utilizing catalytic amounts of novel chiral ligands. Chiral ligands of amino alcohols and aminophosphine gave S-configured cyanosilylated products with up to 84% ee. In contrast, C-2-symmetric ligands resulted in R-configured products with up to 95% ee.-
dc.languageEnglish-
dc.publisherGEORG THIEME VERLAG KG-
dc.subjectOPTICALLY-ACTIVE CYANOHYDRINS-
dc.subjectCHIRAL OXAZABOROLIDINIUM ION-
dc.subjectENANTIOSELECTIVE CYANOSILYLATION-
dc.subjectSTEREOSELECTIVE-SYNTHESIS-
dc.subjectCHEMOENZYMATIC SYNTHESIS-
dc.subjectSYNTHETIC APPLICATIONS-
dc.subjectAMINO-ACIDS-
dc.subjectINHIBITORS-
dc.subjectCONVERSION-
dc.subjectEPHEDRINE-
dc.titleStereofacial control in asymmetric cyanosilylation of aldehydes catalyzed by novel S-proline-derived titanium complexes-
dc.typeArticle-
dc.identifier.wosid000231457700003-
dc.identifier.scopusid2-s2.0-23944494189-
dc.type.rimsART-
dc.citation.volume13-
dc.citation.beginningpage1995-
dc.citation.endingpage1998-
dc.citation.publicationnameSYNLETT-
dc.identifier.doi10.1055/s-2005-871971-
dc.contributor.localauthorKang, SungHo-
dc.contributor.nonIdAuthorKim, YB-
dc.contributor.nonIdAuthorKim, MK-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorasymmetric catalysis-
dc.subject.keywordAuthorcyanohydrin-
dc.subject.keywordAuthorS-proline derivatives-
dc.subject.keywordAuthorstereoselectivity-
dc.subject.keywordAuthorLewis acid/base catalysis-
dc.subject.keywordPlusOPTICALLY-ACTIVE CYANOHYDRINS-
dc.subject.keywordPlusCHIRAL OXAZABOROLIDINIUM ION-
dc.subject.keywordPlusENANTIOSELECTIVE CYANOSILYLATION-
dc.subject.keywordPlusSTEREOSELECTIVE-SYNTHESIS-
dc.subject.keywordPlusCHEMOENZYMATIC SYNTHESIS-
dc.subject.keywordPlusSYNTHETIC APPLICATIONS-
dc.subject.keywordPlusAMINO-ACIDS-
dc.subject.keywordPlusINHIBITORS-
dc.subject.keywordPlusCONVERSION-
dc.subject.keywordPlusEPHEDRINE-
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