DC Field | Value | Language |
---|---|---|
dc.contributor.author | Go, Kany Seok | ko |
dc.contributor.author | Son, Sung Real | ko |
dc.contributor.author | Kim, Sang Done | ko |
dc.date.accessioned | 2013-03-07T08:26:55Z | - |
dc.date.available | 2013-03-07T08:26:55Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-11 | - |
dc.identifier.citation | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v.33, no.21, pp.5986 - 5995 | - |
dc.identifier.issn | 0360-3199 | - |
dc.identifier.uri | http://hdl.handle.net/10203/89788 | - |
dc.description.abstract | Partial oxidation of methane and water splitting for hydrogen production were carried out. The reaction kinetics of reduction and oxidation (redox) of Mn and Zn iron oxides were determined using a thermogravimetric analyzer. The reduction conversion of the metal oxides increases with temperature above 1073 K and all the experimental data are well represented by the diffusion-limited mechanism except ZnFe(2)O(4) due to the solid state diffusion of iron and the reaction with solid carbon. The oxidation reaction was also controlled by the product-layer diffusion mechanism. Substitution of Mn and Zn cations with iron oxides can lower the reaction temperature and increase the reaction rate. The reaction rate and the activation energy (57-110 kJ/mol) for decomposition of water by oxidation of the metal oxides were also determined. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | CHEMICAL-LOOPING COMBUSTION | - |
dc.subject | OXYGEN CARRIER PARTICLES | - |
dc.subject | HIGH-TEMPERATURE | - |
dc.subject | H-2 GENERATION | - |
dc.subject | PURE HYDROGEN | - |
dc.subject | SYNTHESIS GAS | - |
dc.subject | IRON-OXIDES | - |
dc.subject | MECHANISM | - |
dc.subject | METHANE | - |
dc.subject | COPRODUCTION | - |
dc.title | Reaction kinetics of reduction and oxidation of metal oxides for hydrogen production | - |
dc.type | Article | - |
dc.identifier.wosid | 000261115300015 | - |
dc.identifier.scopusid | 2-s2.0-55049140965 | - |
dc.type.rims | ART | - |
dc.citation.volume | 33 | - |
dc.citation.issue | 21 | - |
dc.citation.beginningpage | 5986 | - |
dc.citation.endingpage | 5995 | - |
dc.citation.publicationname | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | - |
dc.identifier.doi | 10.1016/j.ijhydene.2008.05.039 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sang Done | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Hydrogen production | - |
dc.subject.keywordAuthor | Thermogravimetric analysis | - |
dc.subject.keywordAuthor | Redox kinetics of metal oxide | - |
dc.subject.keywordAuthor | Water splitting | - |
dc.subject.keywordAuthor | Mn- and Zn-cation iron oxides | - |
dc.subject.keywordAuthor | Diffusion controlling reaction | - |
dc.subject.keywordPlus | CHEMICAL-LOOPING COMBUSTION | - |
dc.subject.keywordPlus | OXYGEN CARRIER PARTICLES | - |
dc.subject.keywordPlus | HIGH-TEMPERATURE | - |
dc.subject.keywordPlus | H-2 GENERATION | - |
dc.subject.keywordPlus | PURE HYDROGEN | - |
dc.subject.keywordPlus | SYNTHESIS GAS | - |
dc.subject.keywordPlus | IRON-OXIDES | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | METHANE | - |
dc.subject.keywordPlus | COPRODUCTION | - |
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