DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ikeda, Taichi | ko |
dc.contributor.author | Stoddart, James Fraser | ko |
dc.date.accessioned | 2013-03-06T11:57:40Z | - |
dc.date.available | 2013-03-06T11:57:40Z | - |
dc.date.created | 2012-03-14 | - |
dc.date.created | 2012-03-14 | - |
dc.date.issued | 2008-01 | - |
dc.identifier.citation | SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, v.9, no.1 | - |
dc.identifier.issn | 1468-6996 | - |
dc.identifier.uri | http://hdl.handle.net/10203/86904 | - |
dc.description.abstract | Recent investigations on the design and synthesis of electrochromic materials based on switchable three-station [2] catenanes are summarized. The reasoning and preliminary experiments behind the design of electrochemically controllable red-green-blue (RGB), donor-acceptor [2] catenanes are presented. A basis for color generation is discussed in which the tetracationic cyclophane, cyclobis(paraquat-p-phenylene), serves as the pi-electron deficient ring which circumrotates between three pi-electron rich recognition sites within a macrocyclic polyether, generating the three different colors (RGB) based on the different charge transfer interactions between the tetracationic cyclophane and recognition sites based on 1,5-dioxynaphthalene (R), tetrathiafulvalene (G) and benzidine (B). Issues relating to the realization of an RGB [2] catenane are raised and discussed: they include (i) color tuning, (ii) thermodynamic considerations, (iii) electrochemistry on model compounds, (iv) molecular design, (v) the electrochemical behavior of three-station [2] catenanes and (vi) electrochromism in polymer gel matrices. Finally, the challenges that need to be met in the future if the ideal RGB catenane is to be prepared, are outlined. | - |
dc.language | English | - |
dc.publisher | NATL INST MATERIALS SCIENCE | - |
dc.subject | TEMPLATE-DIRECTED SYNTHESIS | - |
dc.subject | ACTIVE-MATRIX DISPLAYS | - |
dc.subject | TETRATHIAFULVALENE UNIT | - |
dc.subject | PLASTIC TRANSISTORS | - |
dc.subject | ELECTRONIC PAPER | - |
dc.subject | DONOR-ACCEPTOR | - |
dc.subject | REDOX | - |
dc.subject | CYCLOBIS(PARAQUAT-P-PHENYLENE) | - |
dc.subject | PSEUDOROTAXANES | - |
dc.subject | CATENANES | - |
dc.title | Electrochromic materials using mechanically interlocked molecules | - |
dc.type | Article | - |
dc.identifier.wosid | 000257128300014 | - |
dc.identifier.scopusid | 2-s2.0-49049107361 | - |
dc.type.rims | ART | - |
dc.citation.volume | 9 | - |
dc.citation.issue | 1 | - |
dc.citation.publicationname | SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS | - |
dc.identifier.doi | 10.1088/1468-6996/9/1/014104 | - |
dc.contributor.nonIdAuthor | Ikeda, Taichi | - |
dc.type.journalArticle | Review | - |
dc.subject.keywordAuthor | interlocked molecules | - |
dc.subject.keywordAuthor | [2] catenanes | - |
dc.subject.keywordAuthor | electrochromism | - |
dc.subject.keywordAuthor | carge-transfer complex | - |
dc.subject.keywordAuthor | electronic paper display | - |
dc.subject.keywordPlus | TEMPLATE-DIRECTED SYNTHESIS | - |
dc.subject.keywordPlus | ACTIVE-MATRIX DISPLAYS | - |
dc.subject.keywordPlus | TETRATHIAFULVALENE UNIT | - |
dc.subject.keywordPlus | PLASTIC TRANSISTORS | - |
dc.subject.keywordPlus | ELECTRONIC PAPER | - |
dc.subject.keywordPlus | DONOR-ACCEPTOR | - |
dc.subject.keywordPlus | REDOX | - |
dc.subject.keywordPlus | CYCLOBIS(PARAQUAT-P-PHENYLENE) | - |
dc.subject.keywordPlus | PSEUDOROTAXANES | - |
dc.subject.keywordPlus | CATENANES | - |
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