DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ahn, T | ko |
dc.contributor.author | Ko, SW | ko |
dc.contributor.author | Lee, J | ko |
dc.contributor.author | Shim, Hong Ku | ko |
dc.date.accessioned | 2013-03-06T05:53:13Z | - |
dc.date.available | 2013-03-06T05:53:13Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2002-04 | - |
dc.identifier.citation | MACROMOLECULES, v.35, no.9, pp.3495 - 3505 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | http://hdl.handle.net/10203/86019 | - |
dc.description.abstract | Novel cyclohexylsilyl- or phenylsilyl-substituted poly(1,4-phenylene vinylene) (PPV) derivatives, poly [2,5-bis(dimethylcyclohexylsilyl)-1,4-phenylene vinylene] (BDMCyS-PPV), poly [2,5-bis(dimethylphenylsilyl)-1,4-phenylene vinylene] (BDMPS-PPV), poly [2-dimethylcyclohexylsilyl-1,4-phenylene vinylene] (DMCyS-PPV), and poly [2-dimethylphenylsilyl-1,4-phenylene vinylene] (DMPS-PPV), were synthesized via the bromine precursor route (BPR) and Gilch dehydrohalogenation polyaddition. Thin films of the insoluble BDMCyS-PPV and BDMPS-PPV were fabricated from soluble polymer precursor materials by thermal conversion, and the electronic properties of these films were investigated. Monosilyl-substituted DMCyS-PPV and DMPS-PPV exhibited good solubility in the conjugated state, good film-forming properties, and high molecular weights. Moreover, they showed better thermal stability and higher values of T-g (DMCyS-PPV, 125 degreesC; DMPS-PPV, 127 degreesC) than other PPV derivatives including alkylsilyl-substituted PPVs; this improved mechanical stability led to good electroluminescence performance. Monocyclohexylsilyl- or phenylsilyl-substituted DMCyS-PPV and DMPS-PPV exhibited sharp PL emissions at about 511 and 513 nm, respectively, along with extremely high photoluminescence (PL) efficiencies in both solution and film (DMCyS-PPV, Phi(film) = 0.83; DMCPS-PPV, Phi(film) = 0.82). LED devices fabricated from DMCyS-PPV and DMPS-PPV using the configuration ITO/polymer/Al showed electroluminescence (EL) maxima at 510 and 515 nm, respectively, with external EL quantum efficiencies of 0.02% and 0.03%. Incorporation of PVK as a hole-transporting layer between the ITO and polymer with an air-stable aluminum cathode caused a substantial improvement in the EL quantum efficiencies, increasing the values to 0.07% for DMCyS-PPV and 0.08% for DMPS-PPV. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | ELECTROLUMINESCENT POLYMERS | - |
dc.subject | ELECTRON INJECTION | - |
dc.subject | EFFICIENT | - |
dc.subject | PHOTOLUMINESCENCE | - |
dc.subject | COPOLYMERS | - |
dc.subject | DEVICES | - |
dc.subject | ALUMINUM | - |
dc.subject | PPVS | - |
dc.title | Novel cyclohexylsilyl- or phenylsilyl-substituted poly(p-phenylene vinylene)s via the halogen precursor route and Gilch polymerization | - |
dc.type | Article | - |
dc.identifier.wosid | 000175112100028 | - |
dc.identifier.scopusid | 2-s2.0-0037161397 | - |
dc.type.rims | ART | - |
dc.citation.volume | 35 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 3495 | - |
dc.citation.endingpage | 3505 | - |
dc.citation.publicationname | MACROMOLECULES | - |
dc.contributor.localauthor | Shim, Hong Ku | - |
dc.contributor.nonIdAuthor | Ahn, T | - |
dc.contributor.nonIdAuthor | Ko, SW | - |
dc.contributor.nonIdAuthor | Lee, J | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | ELECTROLUMINESCENT POLYMERS | - |
dc.subject.keywordPlus | ELECTRON INJECTION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | PHOTOLUMINESCENCE | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | DEVICES | - |
dc.subject.keywordPlus | ALUMINUM | - |
dc.subject.keywordPlus | PPVS | - |
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