Synthesis of poly(arylene ether amide)s containing CF3 groups by nitro displacement reaction of AB-type monomers

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New poly(arylene ether amide)s with trifluoromethyl pendent groups were prepared via nucleophilic nitro displacement reaction of AB-type monomers. 4-Nitro-3-trifluoromethyl-[N-(4-hydroxyphenyl)]benzamide (3) and 4-nitro-3-trifluoro-methyl-[N-(3-hydroxyphenyl)]benzamide (4) gave polymers with weight-average molecular weights over 42 000 g/mol and glass transition temperatures of 269degreesC and 213degreesC, respectively. Both polymers were soluble in common organic solvents including THF, and formed transparent films upon casting.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2002-08
Language
English
Article Type
Article
Keywords

POLY(BIPHENYLENE OXIDE)S; TRIFLUOROMETHYL GROUPS; POLYMERIZATION; POLYMERS

Citation

MACROMOLECULAR RAPID COMMUNICATIONS, v.23, no.12, pp.666 - 671

ISSN
1022-1336
URI
http://hdl.handle.net/10203/83513
Appears in Collection
CH-Journal Papers(저널논문)
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