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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Synthesis and structure of ansa-cyclopentadienyl pyrrolyl titanium complexes: [(eta(5)-C5H4)CH2(2-C4H3N)]Ti(NMe2)(2) and [1,3-{CH2(2-C4H3N)}(2)(eta(5)-C5H3)]Ti(NMe2)

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dc.contributor.authorSeo, WSko
dc.contributor.authorCho, YJko
dc.contributor.authorYoon, SCko
dc.contributor.authorPark, Joon Taikko
dc.contributor.authorPark, Yko
dc.date.accessioned2013-03-04T17:41:24Z-
dc.date.available2013-03-04T17:41:24Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2001-12-
dc.identifier.citationJOURNAL OF ORGANOMETALLIC CHEMISTRY, v.640, no.1-2, pp.79 - 84-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10203/83492-
dc.description.abstractReaction of ansa-cyclopentadienyl pyrrolyl ligand (C5H5)CH2(2-C4H3NH) (2) with Ti(NMe2)(4) affords bis(dimethylamido)titanium complex [(eta (5)-C5H4)CH2(2-C4H3N)]Ti(NMe2)(2) (3) via amine elimination. A cyclopentadiene ligand with two pendant pyrrolyl arms, a mixture of 1,3- and 1,4-(CH2(2-C4H3NH)}(2)C5H4 (4), undergoes an analogous reaction with Ti(NMe2)(4) to give [1,3-{CH2(2-C4H3N)}(2)(eta (5)-C5H3)]Ti(NMe2) (5). Molecular structures of 3 and 5 have been determined by single crystal X-ray diffraction studies. (C) 2001 Elsevier Science B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectAMIDO-FLUORENYL LIGAND-
dc.subjectOLEFIN POLYMERIZATION-
dc.subjectAMINE ELIMINATION-
dc.subjectETHYLENE POLYMERIZATION-
dc.subjectEFFICIENT SYNTHESIS-
dc.subjectCATALYSTS-
dc.subjectZIRCONIUM-
dc.subjectMETALLOCENES-
dc.subjectCOORDINATION-
dc.subjectREACTIVITY-
dc.titleSynthesis and structure of ansa-cyclopentadienyl pyrrolyl titanium complexes: [(eta(5)-C5H4)CH2(2-C4H3N)]Ti(NMe2)(2) and [1,3-{CH2(2-C4H3N)}(2)(eta(5)-C5H3)]Ti(NMe2)-
dc.typeArticle-
dc.identifier.wosid000172884100011-
dc.identifier.scopusid2-s2.0-0003085303-
dc.type.rimsART-
dc.citation.volume640-
dc.citation.issue1-2-
dc.citation.beginningpage79-
dc.citation.endingpage84-
dc.citation.publicationnameJOURNAL OF ORGANOMETALLIC CHEMISTRY-
dc.contributor.localauthorPark, Joon Taik-
dc.contributor.nonIdAuthorSeo, WS-
dc.contributor.nonIdAuthorCho, YJ-
dc.contributor.nonIdAuthorYoon, SC-
dc.contributor.nonIdAuthorPark, Y-
dc.type.journalArticleArticle-
dc.subject.keywordAuthortitanium-
dc.subject.keywordAuthorcyclopentadienyl-
dc.subject.keywordAuthorpyrrolyl-
dc.subject.keywordAuthorcrystal structures-
dc.subject.keywordPlusAMIDO-FLUORENYL LIGAND-
dc.subject.keywordPlusOLEFIN POLYMERIZATION-
dc.subject.keywordPlusAMINE ELIMINATION-
dc.subject.keywordPlusETHYLENE POLYMERIZATION-
dc.subject.keywordPlusEFFICIENT SYNTHESIS-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusZIRCONIUM-
dc.subject.keywordPlusMETALLOCENES-
dc.subject.keywordPlusCOORDINATION-
dc.subject.keywordPlusREACTIVITY-
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