DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bae, BJ | ko |
dc.contributor.author | Park, Joon Taik | ko |
dc.contributor.author | Suh, IH | ko |
dc.date.accessioned | 2013-03-04T17:33:22Z | - |
dc.date.available | 2013-03-04T17:33:22Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2002-04 | - |
dc.identifier.citation | JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.648, no.1-2, pp.214 - 219 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10203/83469 | - |
dc.description.abstract | The reaction of barium or strontium metal in ammonia gas-saturated THF with two equivalents of dimethyl malonate (dmalH) in the presence of tetraethylene glycol dimethyl ether (tetraglyme) or 1,1,4,7,7-pentamethyldiethylenetriamine (pmdt) yields Ba(dmal)(2)(tetraglyme) (1), Ba(dmal)(2)(pmdt) (2). Sr(dmal)(2)(tetraglyme) (3). and Sr(dmal)(2)(pmdt) (4) as colorless crystals in reasonable yields (45-52%). These complexes have been characterized by spectroscopic methods (IR and H-1- and C-13-NMR) and elemental analysis data. Molecular structures of 1, 3, and 4 have been determined by X-ray diffraction studies and have revealed that they are monomeric and the tetraglyme or pmdt ligand wraps around a central metal atom in a meridional plane with the dmal ligands on opposite sides of this plane. (C) 2002 Elsevier Science B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | CHEMICAL-VAPOR-DEPOSITION | - |
dc.subject | BETA-KETOIMINATE COMPLEXES | - |
dc.subject | APPENDED POLYETHER LARIATS | - |
dc.subject | DIKETONATE COMPLEXES | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | ETHEREAL SOLVENTS | - |
dc.subject | BARIUM PRECURSOR | - |
dc.subject | VOLATILE | - |
dc.subject | MOCVD | - |
dc.subject | ADDUCTS | - |
dc.title | Synthesis and characterization of monomeric Ba and Sr complexes with malonate and Lewis base ligands | - |
dc.type | Article | - |
dc.identifier.wosid | 000175170100027 | - |
dc.identifier.scopusid | 2-s2.0-0036533139 | - |
dc.type.rims | ART | - |
dc.citation.volume | 648 | - |
dc.citation.issue | 1-2 | - |
dc.citation.beginningpage | 214 | - |
dc.citation.endingpage | 219 | - |
dc.citation.publicationname | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.contributor.localauthor | Park, Joon Taik | - |
dc.contributor.nonIdAuthor | Bae, BJ | - |
dc.contributor.nonIdAuthor | Suh, IH | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | barium | - |
dc.subject.keywordAuthor | strontium malonate | - |
dc.subject.keywordAuthor | precursor | - |
dc.subject.keywordPlus | CHEMICAL-VAPOR-DEPOSITION | - |
dc.subject.keywordPlus | BETA-KETOIMINATE COMPLEXES | - |
dc.subject.keywordPlus | APPENDED POLYETHER LARIATS | - |
dc.subject.keywordPlus | DIKETONATE COMPLEXES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | ETHEREAL SOLVENTS | - |
dc.subject.keywordPlus | BARIUM PRECURSOR | - |
dc.subject.keywordPlus | VOLATILE | - |
dc.subject.keywordPlus | MOCVD | - |
dc.subject.keywordPlus | ADDUCTS | - |
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