DC Field | Value | Language |
---|---|---|
dc.contributor.author | You, YS | ko |
dc.contributor.author | Kim, D | ko |
dc.contributor.author | Do, Youngkyu | ko |
dc.contributor.author | Oh, SJ | ko |
dc.contributor.author | Hong, CS | ko |
dc.date.accessioned | 2013-03-04T13:18:28Z | - |
dc.date.available | 2013-03-04T13:18:28Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2004-11 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.43, pp.6899 - 6901 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/82767 | - |
dc.description.abstract | A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)](3)[Mo(CN)(8)](2)(.)5H(2)O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)(8)(3-) and Cu(cyclam)(2+) ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear CU3Mo2 unit (J(p) = 3.88 cm(-1)). Interunit ferromagnetic interactions (J(c) = -0.03 cm(-1)) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ' = -0.46 cm(-1)) resulting from interchain interactions are obtained. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | HIGH-SPIN MOLECULES | - |
dc.subject | COORDINATION POLYMERS | - |
dc.subject | MAGNETIC-PROPERTIES | - |
dc.subject | GROUND-STATE | - |
dc.subject | CU-II | - |
dc.subject | FERROMAGNET | - |
dc.subject | BEHAVIOR | - |
dc.subject | CLUSTER | - |
dc.title | One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure | - |
dc.type | Article | - |
dc.identifier.wosid | 000224792900014 | - |
dc.identifier.scopusid | 2-s2.0-7444264768 | - |
dc.type.rims | ART | - |
dc.citation.volume | 43 | - |
dc.citation.beginningpage | 6899 | - |
dc.citation.endingpage | 6901 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic048856i | - |
dc.contributor.localauthor | Do, Youngkyu | - |
dc.contributor.nonIdAuthor | You, YS | - |
dc.contributor.nonIdAuthor | Kim, D | - |
dc.contributor.nonIdAuthor | Oh, SJ | - |
dc.contributor.nonIdAuthor | Hong, CS | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | HIGH-SPIN MOLECULES | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | GROUND-STATE | - |
dc.subject.keywordPlus | CU-II | - |
dc.subject.keywordPlus | FERROMAGNET | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | CLUSTER | - |
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