Lattice parameter as a measure of electrochemical properties of LiMn2O4

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Many factors affect the electrochemical properties of LiMn2O4. Among these factors the amount of Mn3+ is an important factor which largely influences the capacity and capacity fading. However, it is difficult to detect the amount of Mn3+ by chemical titration method. In this research we try to relate the amount of Mn3+ with the lattice parameter. Lattice parameter is easy to measure. Therefore, if the amount of Mn3+. can be deduced by the lattice parameter, it will be very helpful to control and design the electrochemical properties of LiMn2O4.. The results show a good relationship among the lattice parameter, the amount of Mn3+ and the capacity. Thus, lattice parameter could be used to deduce the electrochemical properties of LiMn2O4, although many works are still needed to construct a firm relationship. (C) 2001 Elsevier Science B.V. All rights reserved.
Publisher
ELSEVIER SCIENCE SA
Issue Date
2001
Language
English
Article Type
Article; Proceedings Paper
Keywords

CATHODE

Citation

JOURNAL OF POWER SOURCES, v.1997-08-01, pp.454 - 457

ISSN
0378-7753
DOI
10.1016/S0378-7753(01)00685-1
URI
http://hdl.handle.net/10203/82248
Appears in Collection
RIMS Journal Papers
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