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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A novel nucleophilic substitution of in situ generated 3-tert-butyldimethyl-silyloxyalk-2-enylsulfonium salts with allylindium reagents

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dc.contributor.authorLee, PHko
dc.contributor.authorLee, Kko
dc.contributor.authorKim, Sung Gakko
dc.date.accessioned2013-03-03T14:22:17Z-
dc.date.available2013-03-03T14:22:17Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2001-10-
dc.identifier.citationORGANIC LETTERS, v.3, no.20, pp.3205 - 3207-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/79059-
dc.description.abstractGRAPHICS In situ generated 3-tert-butyidimethylsilyloxyalk-2-enylsulfonium salts derived from the reaction of alpha beta -enones with dimethyl sulfide in the presence of TBSOTf undergo a novel nucleophilic substitution with in situ generated allylindium reagents from indium and allyl halides to give silyl enol ethers of delta,epsilon -unsaturated ketones, which correspond to Michael addition products, in good yields.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectINDIUM-MEDIATED ALLYLATION-
dc.subjectAQUEOUS-MEDIA-
dc.subjectCARBONYL-COMPOUNDS-
dc.subjectALPHA,BETA-UNSATURATED KETONES-
dc.subjectCONJUGATE ADDITION-
dc.subjectORGANIC-SYNTHESIS-
dc.subjectALDEHYDES-
dc.subjectSELECTIVITY-
dc.subjectOLEFINS-
dc.titleA novel nucleophilic substitution of in situ generated 3-tert-butyldimethyl-silyloxyalk-2-enylsulfonium salts with allylindium reagents-
dc.typeArticle-
dc.identifier.wosid000171362600037-
dc.type.rimsART-
dc.citation.volume3-
dc.citation.issue20-
dc.citation.beginningpage3205-
dc.citation.endingpage3207-
dc.citation.publicationnameORGANIC LETTERS-
dc.contributor.localauthorKim, Sung Gak-
dc.contributor.nonIdAuthorLee, PH-
dc.contributor.nonIdAuthorLee, K-
dc.type.journalArticleArticle-
dc.subject.keywordPlusINDIUM-MEDIATED ALLYLATION-
dc.subject.keywordPlusAQUEOUS-MEDIA-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusALPHA,BETA-UNSATURATED KETONES-
dc.subject.keywordPlusCONJUGATE ADDITION-
dc.subject.keywordPlusORGANIC-SYNTHESIS-
dc.subject.keywordPlusALDEHYDES-
dc.subject.keywordPlusSELECTIVITY-
dc.subject.keywordPlusOLEFINS-
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CH-Journal Papers(저널논문)
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