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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Dual enantioselective Diels-Alder process in the cyclization of chiral acrylamide with dienes

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dc.contributor.authorJung, DYko
dc.contributor.authorPark, DHko
dc.contributor.authorKim, SHko
dc.contributor.authorKim, Yong Haeko
dc.date.accessioned2013-03-03T12:20:59Z-
dc.date.available2013-03-03T12:20:59Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2004-11-
dc.identifier.citationJOURNAL OF PHYSICAL ORGANIC CHEMISTRY, v.17, no.11, pp.1017 - 1022-
dc.identifier.issn0894-3230-
dc.identifier.urihttp://hdl.handle.net/10203/78655-
dc.description.abstractDiels-Alder cycloadditions of chiral acrylamides with cyclopentadiene or 2, 3-dimethyl butadiene proceed with high diastereofacial selectivity. Either endo-R or endo-S products have been obtained depending upon the structures of acrylamides and Lewis acids used. The endo form was exclusively obtained over the exo form. The dependence of the mechanism of formation of opposite configurations of endo-R or endo-S products on the Lewis acids is discussed. Copyright (C) 2004 John Wiley Sons, Ltd.-
dc.languageEnglish-
dc.publisherWILEY-BLACKWELL-
dc.subjectASYMMETRIC INDUCTION-
dc.subjectN-ACYLOXAZOLIDINONE-
dc.subjectAUXILIARIES-
dc.subjectDERIVATIVES-
dc.subjectCAMPHOR-
dc.subject2-OXAZOLONE-
dc.subjectDIENOPHILES-
dc.subjectADDITIONS-
dc.subjectMODEL-
dc.subjectALPHA-
dc.titleDual enantioselective Diels-Alder process in the cyclization of chiral acrylamide with dienes-
dc.typeArticle-
dc.identifier.wosid000224994500014-
dc.identifier.scopusid2-s2.0-8344223661-
dc.type.rimsART-
dc.citation.volume17-
dc.citation.issue11-
dc.citation.beginningpage1017-
dc.citation.endingpage1022-
dc.citation.publicationnameJOURNAL OF PHYSICAL ORGANIC CHEMISTRY-
dc.identifier.doi10.1002/poc.828-
dc.contributor.nonIdAuthorJung, DY-
dc.contributor.nonIdAuthorPark, DH-
dc.contributor.nonIdAuthorKim, SH-
dc.type.journalArticleArticle; Proceedings Paper-
dc.subject.keywordAuthordual enantioselective-
dc.subject.keywordAuthorDiels-Alder cyclization-
dc.subject.keywordAuthordiastereofacial selectivity-
dc.subject.keywordAuthorendo-R-
dc.subject.keywordAuthorendo-S-
dc.subject.keywordAuthorLewis acids-
dc.subject.keywordPlusASYMMETRIC INDUCTION-
dc.subject.keywordPlusN-ACYLOXAZOLIDINONE-
dc.subject.keywordPlusAUXILIARIES-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusCAMPHOR-
dc.subject.keywordPlus2-OXAZOLONE-
dc.subject.keywordPlusDIENOPHILES-
dc.subject.keywordPlusADDITIONS-
dc.subject.keywordPlusMODEL-
dc.subject.keywordPlusALPHA-
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