Ordered mesoporous carbon molecular sieves with functionalized surfaces

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Ordered mesoporous carbon molecular sieves designated as CMK-1 and CMK-5 were synthesized by using nanocasting technique with the synthetic procedures reported previously. After carboxylic acid groups were generated on the carbon frameworks through the partial oxidation with nitric acid, pore walls of the mesoporous carbons were functionalized with various organic and organometallic functional groups using esterification and amidization reactions. Mn-Schiff base complex grafted on the mesoporous carbon surface by using ester bond formation showed remarkable catalytic activity for partial oxidation of cyclohexene. The mesoporous carbons were also functionalizable with tetraethylenepentamine (TEPA), which could be used for the effective removal of heavy metal ions.
Publisher
ELSEVIER SCIENCE BV
Issue Date
2003
Language
English
Article Type
Article; Proceedings Paper
Keywords

FIBER SURFACES; TETRAETHYLENEPENTAMINE

Citation

NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS BOOK SERIES: STUDIES IN SURFACE SCIENCE AND CATALYSIS, v.146, pp.37 - 40

ISSN
0167-2991
URI
http://hdl.handle.net/10203/78447
Appears in Collection
CBE-Journal Papers(저널논문)CH-Journal Papers(저널논문)
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