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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Cyclopentadienyl-hydrazido titanium complexes: Tuning of coordination modes of hydrazido ligands to the titanium center

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dc.contributor.authorYoon, SCko
dc.contributor.authorBae, BJko
dc.contributor.authorSuh, IHko
dc.contributor.authorPark, Joon Taikko
dc.date.accessioned2013-03-02T15:35:45Z-
dc.date.available2013-03-02T15:35:45Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1999-05-
dc.identifier.citationORGANOMETALLICS, v.18, no.11, pp.2049 - 2051-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10203/74205-
dc.description.abstractCyclopentadienyl-hydrazido titanium complexes [(eta(5)-C5Me4)SiMe2(NNMe2)]TiR2 (R = NMe2 (2), Cl (3), Me (5)) and [(eta(5)-C5Me4)SiMe2(NNMe2AlMe3]TiMe2 (4) have been prepared: and characterized. Single-crystal X-ray diffraction studies reveal that complexes 2-5 contain eta(1)-hydrazido (2 and 4) and eta(2)-hydrazido (3 and 5) groups depending on the electronic nature of the titanium center. The reaction of 2 with H2O produces a tetrameric organotitanoxane [(eta(5)-C5Me4)(SiMe2NHNMe2)Ti](4)O-6 (6) with an adamantane-like cage structure.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectOLEFIN POLYMERIZATION-
dc.subjectSTRUCTURAL CHARACTERIZATION-
dc.subjectZIRCONIUM COMPLEXES-
dc.subjectEFFICIENT SYNTHESIS-
dc.subjectMOLECULAR-STRUCTURE-
dc.subjectAMINE ELIMINATION-
dc.subjectBIDENTATE-
dc.subjectCATALYSTS-
dc.subjectROUTE-
dc.titleCyclopentadienyl-hydrazido titanium complexes: Tuning of coordination modes of hydrazido ligands to the titanium center-
dc.typeArticle-
dc.identifier.wosid000080587400003-
dc.identifier.scopusid2-s2.0-0000102813-
dc.type.rimsART-
dc.citation.volume18-
dc.citation.issue11-
dc.citation.beginningpage2049-
dc.citation.endingpage2051-
dc.citation.publicationnameORGANOMETALLICS-
dc.contributor.localauthorPark, Joon Taik-
dc.contributor.nonIdAuthorYoon, SC-
dc.contributor.nonIdAuthorBae, BJ-
dc.contributor.nonIdAuthorSuh, IH-
dc.type.journalArticleArticle-
dc.subject.keywordPlusOLEFIN POLYMERIZATION-
dc.subject.keywordPlusSTRUCTURAL CHARACTERIZATION-
dc.subject.keywordPlusZIRCONIUM COMPLEXES-
dc.subject.keywordPlusEFFICIENT SYNTHESIS-
dc.subject.keywordPlusMOLECULAR-STRUCTURE-
dc.subject.keywordPlusAMINE ELIMINATION-
dc.subject.keywordPlusBIDENTATE-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusROUTE-
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