DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Woojin | ko |
dc.contributor.author | Stevens, PS | ko |
dc.contributor.author | Hites, RA | ko |
dc.date.accessioned | 2008-09-02 | - |
dc.date.available | 2008-09-02 | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2003-08 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY A, v.107, no.34, pp.6603 - 6608 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.uri | http://hdl.handle.net/10203/7249 | - |
dc.description.abstract | The rate constants for the gas-phase reactions of phenanthrene, phenanthrene-d(10), and 1-, 2-, 3-, and 9-methylphenanthrenes with the hydroxyl radical were measured using the relative rate technique over the temperature range of 323-403 K and at a total pressure of 760 Torr. On-line mass spectrometry was used to monitor the concentrations of reactants as a function of time. The following Arrhenius expressions have been determined for these reactions (in units of cubic centimeters per molecule per second): (6.46(-1.39)(+1.77)) x 10(-12) exp[(477 +/- 89)/T] for phenanthrene, (3.38(-1.91)(+4.42)) x 10(-12) ex [(745 +/- 301)/T] for phenanthrene-d(10), (0.246(-0.115)(+0.218))x 10(-12) exp[(1420 +/- 242)/T] for 1-methylphenanthrene, (2.54(-1.49)(+3.57)) x 10(-12) exp[(964 +/- 322)/T] for 2-methylphenanthrene, (2.97(-0.56)(+0.69)) x 10(-12) exp[(926 +/- 77)/T] for 3-methylphenanthrene, and (7.75(-5.02)(+14.3)) x 10(-12) exp[(679 +/- 372)/T] for 9-methylphenanthrene. The Arrhenius parameters determined here for phenanthrene-djo and 1-, 2-, 3-, and 9-methylphenanthrene are the first to be reported. | - |
dc.description.sponsorship | The work was supported by a grant from the Atmospheric Chemistry section of the Na-tional Science Foundation (grant number ATM-0106705). | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | POLYCYCLIC AROMATIC-HYDROCARBONS | - |
dc.subject | DIBENZO-P-DIOXINS | - |
dc.subject | ORGANIC-COMPOUNDS | - |
dc.subject | POLYCHLORINATED-BIPHENYLS | - |
dc.subject | ATMOSPHERIC CONDITIONS | - |
dc.subject | REACTION-KINETICS | - |
dc.subject | RADICAL REACTIONS | - |
dc.subject | AIR | - |
dc.subject | PHENANTHRENE | - |
dc.subject | NAPHTHALENE | - |
dc.title | Rate constants for the gas-phase reactions of methylphenanthrenes with OH as a function of temperature | - |
dc.type | Article | - |
dc.identifier.wosid | 000184967600015 | - |
dc.identifier.scopusid | 2-s2.0-0042697591 | - |
dc.type.rims | ART | - |
dc.citation.volume | 107 | - |
dc.citation.issue | 34 | - |
dc.citation.beginningpage | 6603 | - |
dc.citation.endingpage | 6608 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.identifier.doi | 10.1021/jp034159k | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Lee, Woojin | - |
dc.contributor.nonIdAuthor | Stevens, PS | - |
dc.contributor.nonIdAuthor | Hites, RA | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | POLYCYCLIC AROMATIC-HYDROCARBONS | - |
dc.subject.keywordPlus | DIBENZO-P-DIOXINS | - |
dc.subject.keywordPlus | ORGANIC-COMPOUNDS | - |
dc.subject.keywordPlus | POLYCHLORINATED-BIPHENYLS | - |
dc.subject.keywordPlus | ATMOSPHERIC CONDITIONS | - |
dc.subject.keywordPlus | REACTION-KINETICS | - |
dc.subject.keywordPlus | RADICAL REACTIONS | - |
dc.subject.keywordPlus | AIR | - |
dc.subject.keywordPlus | PHENANTHRENE | - |
dc.subject.keywordPlus | NAPHTHALENE | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.