AN ASYMMETRIC-SYNTHESIS OF A KEY INTERMEDIATE TO 1-BETA-METHYLCARBAPENEM ANTIBIOTICS
1 beta-Methylcarbapenem 3 has been enantioselectively synthesized starting from ethoxyethyl ether 8 and methyl (R)-3-iodo-2-methylpropionate via the intramolecular 1,3-dipolar cycloaddition of nitrone 6, in which the requisite chiral centers were settled.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1995-09
- Language
- English
- Article Type
- Article
- Keywords
STEREOCONTROLLED SYNTHESIS; HOMOENOLATE; NITRONE
- Citation
TETRAHEDRON LETTERS, v.36, no.37, pp.6713 - 6716
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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