Facile oxidation of benzyl ethers by the 2-nitrobenzenesulfonylperoxyl intermediate generated from 2-nitrobenzenesulfonyl chloride and superoxide

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Various benzyl ethers react with a 2-nitrobenzenesulfonylperoxyl radical intermediate generated from 2-nitrobenzenesulfonyl chloride and potassium superoxide at -25 degrees C in acetonitrile to give the corresponding esters in high yields.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
1998-02
Language
English
Article Type
Article
Keywords

PEROXYSULFUR INTERMEDIATE; DEPROTECTION; RADICALS; ANION; O-2-.

Citation

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, pp.633 - 634

ISSN
0300-922X
DOI
10.1039/a800106e
URI
http://hdl.handle.net/10203/71590
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