DC Field | Value | Language |
---|---|---|
dc.contributor.author | Pyun, Su Il | ko |
dc.contributor.author | j.-s. bae | ko |
dc.date.accessioned | 2013-02-27T20:33:11Z | - |
dc.date.available | 2013-02-27T20:33:11Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1997 | - |
dc.identifier.citation | JOURNAL OF POWER SOURCES, v.68, no.2, pp.669 - 673 | - |
dc.identifier.issn | 0378-7753 | - |
dc.identifier.uri | http://hdl.handle.net/10203/70702 | - |
dc.description.abstract | The lithium-ion transport in vanadium pentoxide xerogel film electrodes has been investigated by using cyclic voltammetry and electrochemical impedance spectroscopy. The oxide xerogel film electrodes were prepared by spin-coating a viscous gel on an indium tin oxide (ITO) substrate. The spin-coated xerogel films were dried under vacuum at 130 and 270 degrees C, respectively, The lithium intercalation into the xerogel film electrode dried at 270 degrees C is limited by the interfacial reaction at the electrolyte/electrode interface rather than the lithium-ion transport in the oxide electrode. On the other hand, lithium intercalation into the film electrode dried at 130 degrees C is largely limited by the lithium transport in the oxide film, and the chemical diffusivity of the lithium ion in the oxide film was determined to decrease from 10(-10) to 10(-12) cm(2) s(-1) as the electrode potential of the oxide film fell from 3.0 to 2.2 VLi/Li+. The transition of the diffusion-controlled intercalation to the interfacial reaction-controlled intercalation into the oxide xerogel film with decreasing drying temperature was explained in terms of the modification of the oxide lattice to a more open-structured lattice by structural modification of the oxide film by water molecules incorporated into the film. (C) 1997 Elsevier Science S.A. | - |
dc.publisher | Elsevier Science Bv | - |
dc.subject | V2O5 | - |
dc.subject | GELS | - |
dc.title | Electrochemical Lithium Intercalation into Vanadium Pentoxide Xerogel Film | - |
dc.type | Article | - |
dc.identifier.wosid | 000071251300109 | - |
dc.identifier.scopusid | 2-s2.0-0031246312 | - |
dc.type.rims | ART | - |
dc.citation.volume | 68 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 669 | - |
dc.citation.endingpage | 673 | - |
dc.citation.publicationname | JOURNAL OF POWER SOURCES | - |
dc.contributor.nonIdAuthor | j.-s. bae | - |
dc.type.journalArticle | Article; Proceedings Paper | - |
dc.subject.keywordAuthor | lithium intercalation | - |
dc.subject.keywordAuthor | water molecule | - |
dc.subject.keywordAuthor | vanadium pentoxide xerogel films | - |
dc.subject.keywordAuthor | spin coating | - |
dc.subject.keywordAuthor | electrochemical impedance | - |
dc.subject.keywordPlus | V2O5 | - |
dc.subject.keywordPlus | GELS | - |
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