DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, DC | ko |
dc.contributor.author | Lee, KW | ko |
dc.contributor.author | Jung, Kyung Hoon | ko |
dc.contributor.author | Hahn, JW | ko |
dc.date.accessioned | 2013-02-27T18:40:24Z | - |
dc.date.available | 2013-02-27T18:40:24Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1998-08 | - |
dc.identifier.citation | JOURNAL OF CHEMICAL PHYSICS, v.109, no.5, pp.1698 - 1703 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | http://hdl.handle.net/10203/70160 | - |
dc.description.abstract | Degenerate four-wave mixing spectroscopy has been used to study the photodissociation dynamics of tert-butyl hydroperoxide (t-BuOOH) at 266 nm, long-wavelength tail of the ultraviolet (UV) absorption continuum. The nascent rotational distributions, spin-orbit state ratio, and h-doublet population ratio of the OH (X (2 Pi)) fragments have been extracted. No vibrationally excited OH was observed. The rotational distribution peaked at N " = 5. The average rotational energy was estimated to be 4.2% of the available energy. A slight preference for the Pi(-) Lambda-doublet component and a statistical distribution of the spin-orbit states were observed. The experimental observations are similar to those found for OH from H2O2 photodissociation and are consistent with dissociation via a repulsive excited state. (C) 1998 American Institute of Physics. | - |
dc.language | English | - |
dc.publisher | AMER INST PHYSICS | - |
dc.subject | 4-WAVE-MIXING SPECTROSCOPY | - |
dc.subject | SUB-DOPPLER | - |
dc.subject | RELATIVE POPULATIONS | - |
dc.subject | HYDROGEN-PEROXIDE | - |
dc.subject | FIELD LIMIT | - |
dc.subject | SPECTRA | - |
dc.subject | H2O2 | - |
dc.subject | REDUCTION | - |
dc.subject | PROBE | - |
dc.title | Photodissociation dynamics of tert-butyl hydroperoxide at 266 nm: Degenerate four-wave mixing observation of OH state distribution | - |
dc.type | Article | - |
dc.identifier.wosid | 000075066300014 | - |
dc.type.rims | ART | - |
dc.citation.volume | 109 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 1698 | - |
dc.citation.endingpage | 1703 | - |
dc.citation.publicationname | JOURNAL OF CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1063/1.476716 | - |
dc.contributor.nonIdAuthor | Kim, DC | - |
dc.contributor.nonIdAuthor | Lee, KW | - |
dc.contributor.nonIdAuthor | Hahn, JW | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | 4-WAVE-MIXING SPECTROSCOPY | - |
dc.subject.keywordPlus | SUB-DOPPLER | - |
dc.subject.keywordPlus | RELATIVE POPULATIONS | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | FIELD LIMIT | - |
dc.subject.keywordPlus | SPECTRA | - |
dc.subject.keywordPlus | H2O2 | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | PROBE | - |
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