Total synthesis of (+)-furanomycin

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A highly enantioselective total synthesis of (+)-furanomycin 24 has been achieved via the mercury cation-mediated cyclizations of gamma-hydroxy alkene 4 and homoallylic trichloroacetimidate 11 to install the trans-2,5-disubstituted tetrahydrofuran and the (alpha S)-amino acid side chain, respectively.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
1998-04
Language
English
Article Type
Article
Keywords

(+)-POLYOXAMIC ACID; ALLYLIC ALCOHOLS; FURANOMYCIN; REARRANGEMENT; BIOSYNTHESIS; MECHANISM; REAGENTS; ROUTES

Citation

CHEMICAL COMMUNICATIONS, no.7, pp.761 - 762

ISSN
1359-7345
URI
http://hdl.handle.net/10203/69927
Appears in Collection
CH-Journal Papers(저널논문)
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