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College of Engineering(공과대학)Dept. of Nuclear and Quantum Engineering(원자력및양자공학과)NE-Journal Papers(저널논문)

Photoreaction of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne with methanol or acetone

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dc.contributor.authorShim, SangChulko
dc.contributor.authorPark, SKko
dc.date.accessioned2013-02-27T17:46:43Z-
dc.date.available2013-02-27T17:46:43Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1998-06-
dc.identifier.citationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.19, no.6, pp.686 - 689-
dc.identifier.issn0253-2964-
dc.identifier.urihttp://hdl.handle.net/10203/69917-
dc.description.abstractIrradiation of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne (2) in methanol yields two 1:1 photoaddition products (3 and 4) via silacyclopropene intermediate. Photolysis of (2) with acetone in deaerated methylene chloride yields site specific and regioselective 1:1 adducts (7 and 8) via silacyclopropene and 1-sila-1,2-propadiene intermediate, respectively.-
dc.languageEnglish-
dc.publisherKOREAN CHEMICAL SOC-
dc.subjectPHOTOCHEMISTRY-
dc.subjectORGANOPOLYSILANES-
dc.subjectPHOTOLYSIS-
dc.subject1-ARYL-4-(PENTAMETHYLDISILANYL)BUTA-1,3-DIYNES-
dc.subjectPHENYLETHYNYLDISILANES-
dc.subjectSILACYCLOPROPENES-
dc.subjectBEHAVIOR-
dc.titlePhotoreaction of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne with methanol or acetone-
dc.typeArticle-
dc.identifier.wosid000074253600020-
dc.type.rimsART-
dc.citation.volume19-
dc.citation.issue6-
dc.citation.beginningpage686-
dc.citation.endingpage689-
dc.citation.publicationnameBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.contributor.nonIdAuthorPark, SK-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPHOTOCHEMISTRY-
dc.subject.keywordPlusORGANOPOLYSILANES-
dc.subject.keywordPlusPHOTOLYSIS-
dc.subject.keywordPlus1-ARYL-4-(PENTAMETHYLDISILANYL)BUTA-1,3-DIYNES-
dc.subject.keywordPlusPHENYLETHYNYLDISILANES-
dc.subject.keywordPlusSILACYCLOPROPENES-
dc.subject.keywordPlusBEHAVIOR-
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