Total syntheses of (+)-castanospermine and (+)-6-epicastanospermine

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A divergent synthetic route to (+)-castanospermine 1 and (+)-6-epicastanospermine 2 has been developed via phenylselenoamidation of trichloroacetimidate derived from allylic alcohol 7, and dihydroxylations of trans-olefins 14 and 18 to dispose the three contiguous asymmetric centers, one amino group and two hydroxy groups.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
1998
Language
English
Article Type
Article
Keywords

SYNCYTIUM FORMATION; CASTANOSPERMINE; INHIBITION; DERIVATIVES; REPLICATION

Citation

CHEMICAL COMMUNICATIONS, no.13, pp.1353 - 1354

ISSN
1359-7345
DOI
10.1039/a802741b
URI
http://hdl.handle.net/10203/69857
Appears in Collection
CH-Journal Papers(저널논문)
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