Approximate rate constants for cyclizations of alkyl radicals onto benzyl oxime ethers
The approximate rate constants for 5-exo and 6-exo cyclizations of alkyl radicals onto oxime ethers have been kinetically determined to be 4.2x10(7) s(-1) and 2.4x10(6) s(-1) at 80 degrees C, respectively. The competition studies gave similar results, confirming the effectiveness of rate constants obtained from kinetic studies. (C) 1997 Elsevier Science Ltd.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1997-04
- Language
- English
- Article Type
- Article
- Keywords
N-AZIRIDINYL IMINES; COMPETITION; SECONDARY; KETONES; CARBON; 5-EXO; BOND
- Citation
TETRAHEDRON LETTERS, v.38, no.14, pp.2487 - 2490
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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