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College of Engineering(공과대학)Dept. of Nuclear and Quantum Engineering(원자력및양자공학과)NE-Journal Papers(저널논문)

Approximate rate constants for cyclizations of alkyl radicals onto benzyl oxime ethers

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dc.contributor.authorKim, Sung Gakko
dc.contributor.authorKim, Yko
dc.contributor.authorYoon, KSko
dc.date.accessioned2013-02-27T16:23:25Z-
dc.date.available2013-02-27T16:23:25Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1997-04-
dc.identifier.citationTETRAHEDRON LETTERS, v.38, no.14, pp.2487 - 2490-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10203/69574-
dc.description.abstractThe approximate rate constants for 5-exo and 6-exo cyclizations of alkyl radicals onto oxime ethers have been kinetically determined to be 4.2x10(7) s(-1) and 2.4x10(6) s(-1) at 80 degrees C, respectively. The competition studies gave similar results, confirming the effectiveness of rate constants obtained from kinetic studies. (C) 1997 Elsevier Science Ltd.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectN-AZIRIDINYL IMINES-
dc.subjectCOMPETITION-
dc.subjectSECONDARY-
dc.subjectKETONES-
dc.subjectCARBON-
dc.subject5-EXO-
dc.subjectBOND-
dc.titleApproximate rate constants for cyclizations of alkyl radicals onto benzyl oxime ethers-
dc.typeArticle-
dc.identifier.wosidA1997WR56700027-
dc.type.rimsART-
dc.citation.volume38-
dc.citation.issue14-
dc.citation.beginningpage2487-
dc.citation.endingpage2490-
dc.citation.publicationnameTETRAHEDRON LETTERS-
dc.identifier.doi10.1016/S0040-4039(97)00373-0-
dc.contributor.localauthorKim, Sung Gak-
dc.contributor.nonIdAuthorKim, Y-
dc.contributor.nonIdAuthorYoon, KS-
dc.type.journalArticleArticle-
dc.subject.keywordPlusN-AZIRIDINYL IMINES-
dc.subject.keywordPlusCOMPETITION-
dc.subject.keywordPlusSECONDARY-
dc.subject.keywordPlusKETONES-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlus5-EXO-
dc.subject.keywordPlusBOND-
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