Approximate rate constants for cyclizations of alkyl radicals onto benzyl oxime ethers

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The approximate rate constants for 5-exo and 6-exo cyclizations of alkyl radicals onto oxime ethers have been kinetically determined to be 4.2x10(7) s(-1) and 2.4x10(6) s(-1) at 80 degrees C, respectively. The competition studies gave similar results, confirming the effectiveness of rate constants obtained from kinetic studies. (C) 1997 Elsevier Science Ltd.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
1997-04
Language
English
Article Type
Article
Keywords

N-AZIRIDINYL IMINES; COMPETITION; SECONDARY; KETONES; CARBON; 5-EXO; BOND

Citation

TETRAHEDRON LETTERS, v.38, no.14, pp.2487 - 2490

ISSN
0040-4039
DOI
10.1016/S0040-4039(97)00373-0
URI
http://hdl.handle.net/10203/69574
Appears in Collection
CH-Journal Papers(저널논문)
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