Novel Reductive Cleavage Reaction of α-Halo Epoxides with SMI2: Synthesis of Cyclopropanols

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Aryl substituted alpha-halo epoxide reacted with SmI2 to give the cyclopropanols in the presence of HMPA, while allyl alcohols were yielded in the absence of HMPA.
Publisher
GEORG THIEME VERLAG KG
Issue Date
1998-10
Language
English
Article Type
Article
Keywords

ALPHA,BETA-EPOXY KETONES; SAMARIUM DIIODIDE; CATALYZED-REARRANGEMENT; ORGANIC-SYNTHESIS; RADICAL REACTIONS; EFFICIENT ROUTE; BOND-CLEAVAGE; ESTERS; CYCLOPENTANOLS; FRAGMENTATION

Citation

SYNLETT, no.10, pp.1073

ISSN
0936-5214
URI
http://hdl.handle.net/10203/68461
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