DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Sung Gak | ko |
dc.contributor.author | Yoon, JY | ko |
dc.date.accessioned | 2013-02-27T11:55:06Z | - |
dc.date.available | 2013-02-27T11:55:06Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2000-10 | - |
dc.identifier.citation | SYNTHESIS-STUTTGART, pp.1622 - 1630 | - |
dc.identifier.issn | 0039-7881 | - |
dc.identifier.uri | http://hdl.handle.net/10203/68412 | - |
dc.description.abstract | Carbenes, generated from thermolysis of alpha-oxacyclo- and alpha-azacyclo-N-aziridinylimines in refluxing toluene, underwent ring expansions via insertion of alkyl carbenes into carbon-carbon bonds and intramolecular ammonium ylide formations, respectively. Ring expansion reaction of alpha-oxetanyl-N-aziridinylimines occurred via alkylidenecarbene intermediates, whereas thermal reaction of alpha-azetidinyl-N-aziridinylimines afforded alpha-aminoacetylene compounds via 1,2-H migration of alkylidenecarbene intermediates. | - |
dc.language | English | - |
dc.publisher | GEORG THIEME VERLAG | - |
dc.subject | RADICAL CYCLIZATION | - |
dc.subject | 2,3> | - |
dc.subject | -SIGMATROPIC REARRANGEMENT | - |
dc.subject | TRISUBSTITUTED OLEFINS | - |
dc.subject | EFFICIENT SYNTHESIS | - |
dc.subject | CATALYTIC METHODS | - |
dc.subject | ALLYL COMPOUNDS | - |
dc.subject | OXYGEN YLIDES | - |
dc.subject | IMINES | - |
dc.subject | ROUTE | - |
dc.subject | GENERATION | - |
dc.title | Carbene reactions of alpha-oxacyclo- and alpha-azacyclo-N-aziridinylimines: Effect of heteroatom and ring size in the ring expansion reaction | - |
dc.type | Article | - |
dc.identifier.wosid | 000089804300024 | - |
dc.type.rims | ART | - |
dc.citation.beginningpage | 1622 | - |
dc.citation.endingpage | 1630 | - |
dc.citation.publicationname | SYNTHESIS-STUTTGART | - |
dc.contributor.localauthor | Kim, Sung Gak | - |
dc.contributor.nonIdAuthor | Yoon, JY | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | carbenes | - |
dc.subject.keywordAuthor | heterocycles | - |
dc.subject.keywordAuthor | hydrazones | - |
dc.subject.keywordAuthor | ring expansions | - |
dc.subject.keywordAuthor | ylides | - |
dc.subject.keywordPlus | RADICAL CYCLIZATION | - |
dc.subject.keywordPlus | 2,3> | - |
dc.subject.keywordPlus | -SIGMATROPIC REARRANGEMENT | - |
dc.subject.keywordPlus | TRISUBSTITUTED OLEFINS | - |
dc.subject.keywordPlus | EFFICIENT SYNTHESIS | - |
dc.subject.keywordPlus | CATALYTIC METHODS | - |
dc.subject.keywordPlus | ALLYL COMPOUNDS | - |
dc.subject.keywordPlus | OXYGEN YLIDES | - |
dc.subject.keywordPlus | IMINES | - |
dc.subject.keywordPlus | ROUTE | - |
dc.subject.keywordPlus | GENERATION | - |
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