Efficient synthesis of dl-zizaene sesquiterpenes via tandem radical cyclizations of N-aziridinylimines

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Tandem radical cyclizations of N-aziridinylimine 7, 17, and 21 with Bu3SnH/AIBN provided bicyclo[3.2.1]octanes and tricyclo[6.2.1.0(1,5)]undecanes, respectively and led to the stereocontrolled synthesis of dl-zizaene and dl-khusimone.
Publisher
GEORG THIEME VERLAG
Issue Date
1997-08
Language
English
Article Type
Article
Keywords

METHYLENECYCLOPROPANE DERIVATIVES; ZIZAANE SESQUITERPENES; IMINES; (-)-KHUSIMONE; TRIQUINANES; ROUTE

Citation

SYNLETT, no.8, pp.947 - 947

ISSN
0936-5214
URI
http://hdl.handle.net/10203/68002
Appears in Collection
CH-Journal Papers(저널논문)
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