DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김동섭 | ko |
dc.contributor.author | 이상엽 | ko |
dc.date.accessioned | 2013-02-27T03:33:22Z | - |
dc.date.available | 2013-02-27T03:33:22Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1991-01 | - |
dc.identifier.citation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.12, no.6, pp.692 - 698 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://hdl.handle.net/10203/66207 | - |
dc.description.abstract | The reaction path Smoluchowski equation approach developed in a recent work to calculate the rate constant for a diffusive multidimensional barrier crossing process is extended to incorporate the configuration-dependent diffusion matrix. The resulting formalism is then applied to the investigation of stilbene photoisomerization dynamics. Adapting a model two-dimensional potential and a model diffusion matrix proposed by Agmon and Kosloff (J. Phys. Chem.,91 (1987) 1988), we derive an eigenvalue equlation for the relaxation rate constant of the stilbene photoisomerization. This eigenvalue equation is solved numerically by using the finite element method. The advantages and limitations of the present method are discussed. | - |
dc.language | English | - |
dc.publisher | 대한화학회 | - |
dc.title | Application of reaction path Smoluchowski equation formalism to the photoisomerization of trans-Stilbene | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.citation.volume | 12 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 692 | - |
dc.citation.endingpage | 698 | - |
dc.citation.publicationname | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.contributor.localauthor | 김동섭 | - |
dc.contributor.nonIdAuthor | 이상엽 | - |
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