DC Field | Value | Language |
---|---|---|
dc.contributor.author | KWON, OS | ko |
dc.contributor.author | GHO, CG | ko |
dc.contributor.author | Choi, Byong-Seok | ko |
dc.contributor.author | CHOI, SK | ko |
dc.date.accessioned | 2013-02-25T04:40:45Z | - |
dc.date.available | 2013-02-25T04:40:45Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1994-06 | - |
dc.identifier.citation | MACROMOLECULAR CHEMISTRY AND PHYSICS, v.195, no.6, pp.2187 - 2194 | - |
dc.identifier.issn | 1022-1352 | - |
dc.identifier.uri | http://hdl.handle.net/10203/59931 | - |
dc.description.abstract | The polymerization of styrene was studied by using a bifunctional initiator, 1,4-bis(1-chloroethyl)benzene (1). It was demonstrated that living polymerization can be achieved in the styrene/l/SnCl4 system in chloroform at - 15-degrees-C in the presence of 2,6-di-tert-butylpyridine. The number-average molecular weight of the obtained polymers increases with monomer conversion and with addition of a fresh feed of monomer at the end of the first-stage polymerization. The molecular weight distribution (MWD) of the obtained polymers is narrow (ratio of weight- to number-average molecular weights (M(w)BAR/M(n)BAR < 1,2) throughout the polymerization. In the absence of 2,6-di-tert-butylpyridine, the initiating system results polystyrene with a bimodal MWD. Also a bimodal MWD was obtained with H2O/SnCl4 as initiating system. 2,6-Di-tert-butylpyridine in conjunction with H2O/SnCl4 does not lead to polymerization. | - |
dc.language | English | - |
dc.publisher | HUTHIG WEPF VERLAG | - |
dc.subject | ISOBUTYL VINYL ETHER | - |
dc.subject | CARBOCATIONIC POLYMERIZATION | - |
dc.subject | METHYLSTYRENE | - |
dc.subject | CHLORIDE | - |
dc.subject | HALIDES | - |
dc.title | LIVING CATIONIC POLYMERIZATION OF STYRENE BY THE BIFUNCTIONAL INITIATING SYSTEM 1,4-BIS(1-CHLOROETHYL)BENZENE SNCL4 IN THE PRESENCE OF 2,6-DI-TERT-BUTYLPYRIDINE | - |
dc.type | Article | - |
dc.identifier.wosid | A1994NT13800025 | - |
dc.type.rims | ART | - |
dc.citation.volume | 195 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 2187 | - |
dc.citation.endingpage | 2194 | - |
dc.citation.publicationname | MACROMOLECULAR CHEMISTRY AND PHYSICS | - |
dc.contributor.localauthor | Choi, Byong-Seok | - |
dc.contributor.nonIdAuthor | KWON, OS | - |
dc.contributor.nonIdAuthor | GHO, CG | - |
dc.contributor.nonIdAuthor | CHOI, SK | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | ISOBUTYL VINYL ETHER | - |
dc.subject.keywordPlus | CARBOCATIONIC POLYMERIZATION | - |
dc.subject.keywordPlus | METHYLSTYRENE | - |
dc.subject.keywordPlus | CHLORIDE | - |
dc.subject.keywordPlus | HALIDES | - |
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