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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

PHOTOLYSIS OF ETHYL CHLORIDE AT 121.6-NM

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dc.contributor.authorCHOI, SSko
dc.contributor.authorOH, DGko
dc.contributor.authorKIM, SKko
dc.contributor.authorJung, Kyung Hoonko
dc.date.accessioned2013-02-25T02:39:09Z-
dc.date.available2013-02-25T02:39:09Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1992-03-
dc.identifier.citationJOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v.64, no.2, pp.135 - 143-
dc.identifier.issn1010-6030-
dc.identifier.urihttp://hdl.handle.net/10203/59175-
dc.description.abstractThe photolysis of ethyl chloride at 121.6 nm was studied over the pressure range 60-4000 Pa at room temperature using a hydrogen atom resonance lamp. The pressure effect was investigated with CO2 and SF6. The scavenger effect of the reaction was also observed by adding NO gas. The major products of the reaction were CH4, C2H2, C2H4 and C2H6. The branching ratios between the elimination and the radical processes were found to be 0.68-0.32. The fraction of hot ethylene (above the critical energy) was found to be about 30%.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA LAUSANNE-
dc.subjectVIBRATIONAL ENERGY-TRANSFER-
dc.subjectGAS-PHASE-
dc.subjectDECOMPOSITION REACTION-
dc.subjectGASEOUS BROMOETHANE-
dc.subject193.1 NM-
dc.subject147 NM-
dc.subjectBROMIDE-
dc.subjectPHOTODECOMPOSITION-
dc.subjectISOMERIZATION-
dc.titlePHOTOLYSIS OF ETHYL CHLORIDE AT 121.6-NM-
dc.typeArticle-
dc.identifier.wosidA1992HM82100001-
dc.type.rimsART-
dc.citation.volume64-
dc.citation.issue2-
dc.citation.beginningpage135-
dc.citation.endingpage143-
dc.citation.publicationnameJOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY-
dc.identifier.doi10.1016/1010-6030(92)85101-Y-
dc.contributor.nonIdAuthorCHOI, SS-
dc.contributor.nonIdAuthorOH, DG-
dc.contributor.nonIdAuthorKIM, SK-
dc.type.journalArticleArticle-
dc.subject.keywordPlusVIBRATIONAL ENERGY-TRANSFER-
dc.subject.keywordPlusGAS-PHASE-
dc.subject.keywordPlusDECOMPOSITION REACTION-
dc.subject.keywordPlusGASEOUS BROMOETHANE-
dc.subject.keywordPlus193.1 NM-
dc.subject.keywordPlus147 NM-
dc.subject.keywordPlusBROMIDE-
dc.subject.keywordPlusPHOTODECOMPOSITION-
dc.subject.keywordPlusISOMERIZATION-
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