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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

NOVEL EXO-NIDO-CUPRACARBORANE WITH AN UNUSUAL SOLUTION FLUXIONALITY - SYNTHESIS AND STRUCTURE OF [9,10-EXO-(CU(PPH3)2)-9,10-(MU-H)2-7,8-NIDO-C2B9H10]

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dc.contributor.authorPARK, YWko
dc.contributor.authorKIM, Jko
dc.contributor.authorKIM, Sko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2013-02-24T10:55:34Z-
dc.date.available2013-02-24T10:55:34Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1993-01-
dc.identifier.citationCHEMISTRY LETTERS, v.22, no.1, pp.121 - 124-
dc.identifier.issn0366-7022-
dc.identifier.urihttp://hdl.handle.net/10203/56633-
dc.description.abstractSynthetic routes to [9,10-exo -{Cu(PPh3)2}-9,10-(mu-H)2-7,8-nido-C2B9H10] which displays an unusual solution dynamic property have been devised. The molecular structure and composition of the novel d10 exo-nido-cupracarborane, established by single-crystal X-ray analysis and B-11 NMR spectroscopy, reveal the eta2-hapticity of nido-C2B9 cage toward an exo-Cu(PPh3)2 moiety as well as the presence of the 12th H atom.-
dc.languageEnglish-
dc.publisherCHEMICAL SOC JAPAN-
dc.subjectSOLID-STATE STRUCTURE-
dc.subjectCRYSTALLINE TL2B2H9C2ME2-
dc.subjectTL(I)-TL(I) INTERACTIONS-
dc.subjectDICARBOLLYL COMPLEXES-
dc.subjectELEMENTS PHOSPHORUS-
dc.subjectMOLECULAR-STRUCTURE-
dc.subjectMETALLACARBORANE-
dc.subjectCLAS&lt-
dc.subjectC2ME2B9H9&gt-
dc.subjectREACTIVITY-
dc.titleNOVEL EXO-NIDO-CUPRACARBORANE WITH AN UNUSUAL SOLUTION FLUXIONALITY - SYNTHESIS AND STRUCTURE OF [9,10-EXO-(CU(PPH3)2)-9,10-(MU-H)2-7,8-NIDO-C2B9H10]-
dc.typeArticle-
dc.identifier.wosidA1993KK06300033-
dc.type.rimsART-
dc.citation.volume22-
dc.citation.issue1-
dc.citation.beginningpage121-
dc.citation.endingpage124-
dc.citation.publicationnameCHEMISTRY LETTERS-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorPARK, YW-
dc.contributor.nonIdAuthorKIM, J-
dc.contributor.nonIdAuthorKIM, S-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSOLID-STATE STRUCTURE-
dc.subject.keywordPlusCRYSTALLINE TL2B2H9C2ME2-
dc.subject.keywordPlusTL(I)-TL(I) INTERACTIONS-
dc.subject.keywordPlusDICARBOLLYL COMPLEXES-
dc.subject.keywordPlusELEMENTS PHOSPHORUS-
dc.subject.keywordPlusMOLECULAR-STRUCTURE-
dc.subject.keywordPlusMETALLACARBORANE-
dc.subject.keywordPlusCLAS&lt-
dc.subject.keywordPlusC2ME2B9H9&gt-
dc.subject.keywordPlusREACTIVITY-
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