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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

First tetrathiolate-bridged dinuclear molybdacarbaboranes: scission and formation of the C-C cluster bond during oxidation processes

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dc.contributor.authorKim, JHko
dc.contributor.authorLamrani, Mko
dc.contributor.authorHwang, JWko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2008-04-15T06:05:34Z-
dc.date.available2008-04-15T06:05:34Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1997-09-
dc.identifier.citationCHEMICAL COMMUNICATIONS, pp.1761 - 1762-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/3872-
dc.description.abstractUnprecedented tetrathiolate-bridged dinuclear ionic molybdacarbaboranes [(C2B9H11)Mo(SPh)(2)](2)(n-) (n = 2, 1) are prepared by successive oxidation of [(C2B9H11)Mo-II-(CO)(2)(SPh)(2)](2-) with diphenyl disulfide and iodosylbenzene: X-ray crystal structure determinations and NMR studies show unusual scission and reformation of the C-C carbaborane cage bond.-
dc.description.sponsorshipSupport of this work by the Korea Science and Engineering Foundationen
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectNUCLEAR MAGNETIC-RESONANCE-
dc.subjectCOMPLEXES-
dc.subjectMOLYBDENUM-
dc.subjectCHEMISTRY-
dc.subjectPRODUCTS-
dc.titleFirst tetrathiolate-bridged dinuclear molybdacarbaboranes: scission and formation of the C-C cluster bond during oxidation processes-
dc.typeArticle-
dc.identifier.wosidA1997XX93400032-
dc.type.rimsART-
dc.citation.beginningpage1761-
dc.citation.endingpage1762-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorKim, JH-
dc.contributor.nonIdAuthorLamrani, M-
dc.contributor.nonIdAuthorHwang, JW-
dc.type.journalArticleArticle-
dc.subject.keywordPlusNUCLEAR MAGNETIC-RESONANCE-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMOLYBDENUM-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusPRODUCTS-
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