First lanthanide complexes and unusual coordination behavior of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene

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dc.contributor.authorKoo, BHko
dc.contributor.authorByun, Yko
dc.contributor.authorHong, Eko
dc.contributor.authorKim, Yko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2008-04-15T06:01:04Z-
dc.date.available2008-04-15T06:01:04Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1998-06-
dc.identifier.citationCHEMICAL COMMUNICATIONS, no.11, pp.1227 - 1228-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/3868-
dc.description.abstractReaction of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene (L) with LnCl(3) (Ln = La, Ce, Nd, Sm) affords new mononuclear lanthanophosphazenes [L.LnCl(3)] with hendecahedral coordination polyhedron in which the ligand L employs an unprecedented kappa(5)N binding core consisting of one cyclotriphosphazene ring nitrogen atom and four pyridinic nitrogen atoms of two sets of geminal pyrazolyl groups.-
dc.description.sponsorshipfinancial support provided by the Korea Science and Engineering Foundation.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherROYAL SOC CHEMISTRY-
dc.titleFirst lanthanide complexes and unusual coordination behavior of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene-
dc.typeArticle-
dc.identifier.wosid000074060800030-
dc.type.rimsART-
dc.citation.issue11-
dc.citation.beginningpage1227-
dc.citation.endingpage1228-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/a801988f-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorKoo, BH-
dc.contributor.nonIdAuthorByun, Y-
dc.contributor.nonIdAuthorHong, E-
dc.contributor.nonIdAuthorKim, Y-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusPALLADIUM(II) CHLORIDE-
dc.subject.keywordPlusCOPPER(II) COMPLEXES-
dc.subject.keywordPlusPHOSPHAZENES-
dc.subject.keywordPlusMONONUCLEAR-
dc.subject.keywordPlusRING-
dc.subject.keywordPlusSPECTROSCOPY-
dc.subject.keywordPlusBIS(PYRAZOLYL)CYCLOTRIPHOSPHAZENES-
dc.subject.keywordPlusCYCLOTRIPHOSPHAZENES-
dc.subject.keywordPlusELECTROCHEMISTRY-
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