Biphenylene-bridged dinuclear group 4 metal complexes: Enhanced polymerization properties in olefin polymerization

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dc.contributor.authorLee, MHko
dc.contributor.authorKim, SKko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2008-04-02T07:53:41Z-
dc.date.available2008-04-02T07:53:41Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-07-
dc.identifier.citationORGANOMETALLICS, v.24, no.15, pp.3618 - 3620-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10203/3626-
dc.description.abstractThe well-defined, novel dinuclear group 4 metal complexes [4,4'-(C6H4)(2)(C5Me4)(2)][CpZrX2](2) (X = Cl (2a), Me (2b)), [4,4'-(C6H4)(2)(C5Me4)(2)][TiCl3](2) (3), and [4,4'-(C6H4)(2)(C5Me4)(2)][Ti(O-2,6-(Pr2Ph)-Pr-i)Cl-2](2) (4) exhibit an increase of molecular weight as well as comparable or even higher catalytic activity in ethylene (2 and 4) and styrene (3 and 4) polymerization than their mononuclear counterparts.-
dc.description.sponsorshipFinancial support from the Korea Science and Engineering Foundation (Grant No. R02-2002-000-00057-0), the CMDS, and the BK 21 project are gratefully acknowledged.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherAMER CHEMICAL SOC-
dc.subjectSTYRENE POLYMERIZATION-
dc.subjectCOMONOMER ENCHAINMENT-
dc.subjectBINUCLEAR CATALYSTS-
dc.subjectZIRCONOCENES-
dc.subjectCOPOLYMERIZATION-
dc.subjectMETALLOCENES-
dc.subjectCOCATALYSTS-
dc.subjectSELECTIVITY-
dc.subjectPROPYLENE-
dc.subjectBEHAVIOR-
dc.titleBiphenylene-bridged dinuclear group 4 metal complexes: Enhanced polymerization properties in olefin polymerization-
dc.typeArticle-
dc.identifier.wosid000230495600003-
dc.identifier.scopusid2-s2.0-22944462047-
dc.type.rimsART-
dc.citation.volume24-
dc.citation.issue15-
dc.citation.beginningpage3618-
dc.citation.endingpage3620-
dc.citation.publicationnameORGANOMETALLICS-
dc.identifier.doi10.1021/om049316w-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorLee, MH-
dc.contributor.nonIdAuthorKim, SK-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSTYRENE POLYMERIZATION-
dc.subject.keywordPlusCOMONOMER ENCHAINMENT-
dc.subject.keywordPlusBINUCLEAR CATALYSTS-
dc.subject.keywordPlusZIRCONOCENES-
dc.subject.keywordPlusCOPOLYMERIZATION-
dc.subject.keywordPlusMETALLOCENES-
dc.subject.keywordPlusCOCATALYSTS-
dc.subject.keywordPlusSELECTIVITY-
dc.subject.keywordPlusPROPYLENE-
dc.subject.keywordPlusBEHAVIOR-
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