DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Jung, Kyung-Hoon | - |
dc.contributor.advisor | 정경훈 | - |
dc.contributor.author | Lee, Taek-Gi | - |
dc.contributor.author | 이택기 | - |
dc.date.accessioned | 2011-12-13T04:59:59Z | - |
dc.date.available | 2011-12-13T04:59:59Z | - |
dc.date.issued | 1994 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=69188&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32675 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1994.2, [ vi, 50 p. ] | - |
dc.description.abstract | Reactions proceeding within chlorobenzene clusters were observed. Electron-impact-ionized dimer produced a variety of products according to the elimination of chlorine atoms and hydrogens. In 193nm laser photoionization, appreciable amount of H elimination product was observed even in unclustered case, which is very rare in halobenzene molecules. It has been proved that molecular elimination of $Cl_2$ contribute to the production of $(C_6H_n-C_6H_5)^{+}$, (n is 3 - 5). Intracluster reactions showed somewhat different products from the gas phase analogue. For evaluation of thermochemical data which are not available, we have determined the stable structure of $(C_6H_5Cl)_2$ and calculated its binding energy, 2.2582 kcal/mol, with PM3 semiempirical calculation. Further works on ionic species are remained for the future. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Intracluster reactions within ionized chlorobenzene clusters | - |
dc.title.alternative | 이온화된 클로로벤젠 분자군 내에서의 반응 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 69188/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000923397 | - |
dc.contributor.localauthor | Jung, Kyung-Hoon | - |
dc.contributor.localauthor | 정경훈 | - |
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