Synthesis and reaction of α-chloro sulfinyl phosphonate알파 클로로 설피닐 포스폰네이트의 합성과 반응

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As part of a continuing study of $\alpha$-Heteratom substituted phosphonates, $\alpha$-chloro sulfinyl methane phosphonates were prepared by two methods. The reaction of $\alpha$-chloro thio methane phosphonates with m-chloroperbenzoic acid afford them. Sulfuryl chloride and silver nitrate also convert arylthio methane phosphonates to the corresponding $\alpha$-chloro sulfinyl methane phosphonates by one step reaction. $\alpha$-chloro sulfinyl methane phosphonates undergo the Pummerer rearrangement, proving an entry to phosphonyl thiolformates. Also, $\alpha$-chloro $\alpha,\,\beta$-unsaturated sulfoxides were prepared in good yields by the Horner-Wittig reaction.
Advisors
Oh, Dong-Young오동영
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1994
Identifier
69186/325007 / 000923363
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1994.2, [ v, 64 p. ]

URI
http://hdl.handle.net/10203/32673
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=69186&flag=dissertation
Appears in Collection
CH-Theses_Master(석사논문)
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