DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Shim, Sang-Chul | - |
dc.contributor.advisor | 심상철 | - |
dc.contributor.author | Lee, Sang-Jin | - |
dc.contributor.author | 이상진 | - |
dc.date.accessioned | 2011-12-13T04:57:43Z | - |
dc.date.available | 2011-12-13T04:57:43Z | - |
dc.date.issued | 1988 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=66058&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32521 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1988.2, [ v, 42 p. ] | - |
dc.description.abstract | A thioamide, N-5-trifluoromethyl-6-methoxy-1-thionaphthoyl-N-methylglycine, undergoes trans $\leftrightharpoons$ cis photoisomerization around C-N bond in solution. Azulene quenching experiments showed that the photoisomerization proceeds via both singlet and triplet excited states. The total quantium yield of the trans cis photoisomerization is about 0.26, 0.14 from pure singlet excited state and 0.12 from pure triplet excited state. Intersystem crossing and internal conversion quantum yields were calculated from sensitized photostationary state experiments and a plausible mechanism is proposed which is supported by external heavy atom effect. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Rotational photoisomerization mechanism of a thioamide, N-5-trifluoromethyl-6-methoxy-1-thionaphthoyl-N-methylglycine | - |
dc.title.alternative | 톨레스타트의 회전광이성질화 반응의 메카니즘에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 66058/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000861303 | - |
dc.contributor.localauthor | Shim, Sang-Chul | - |
dc.contributor.localauthor | 심상철 | - |
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