DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Kim, Sung-Gak | - |
dc.contributor.advisor | 김성각 | - |
dc.contributor.author | Lee, Tai-Au | - |
dc.contributor.author | 이태오 | - |
dc.date.accessioned | 2011-12-13T04:57:41Z | - |
dc.date.available | 2011-12-13T04:57:41Z | - |
dc.date.issued | 1988 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=66056&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32519 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1988.2, [ iv, 63 p. ] | - |
dc.description.abstract | β-Lactam formation via the dehydration of β-amino acids has been developed using organophosphosphorous condensing reagents, benzotriazolyloxytris [dimethylamino] phosphonium hexafluorophosphate (BOP) and triphenylphosphine/N-bromosuccinimide ($Ph_3P$/NBS) system. BOP reagent has been found to be exceedingly effective for the preparation of various β-lactams from β-amino acids. Especially, N-substituted β-amino acids give good yields and high dilution and high temperature are more favorable. Also, $Ph_3P$/NBS method include a successful application of a triphenylphosphine as a condensing agent for the formation of β-lactams from β-amino acids, easy separation of β-lactams from the reaction mixture, mild conditions and high yields in short time for N-substituted β-amino acids under low dilution. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Synthesis of β-lactams from β-amino acids using organophosphorous reagents | - |
dc.title.alternative | 유기인계의 시약을 축합제로 이용한 베타-아미노산으로 부터 베타-락탐의 합성 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 66056/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000861726 | - |
dc.contributor.localauthor | Kim, Sung-Gak | - |
dc.contributor.localauthor | 김성각 | - |
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