DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Shim, Sang-Chul | - |
dc.contributor.advisor | 심상철 | - |
dc.contributor.author | Kim, Eun-Il | - |
dc.contributor.author | 김은일 | - |
dc.date.accessioned | 2011-12-13T04:57:03Z | - |
dc.date.available | 2011-12-13T04:57:03Z | - |
dc.date.issued | 1987 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=65512&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32475 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1987.2, [ iii, 66 p. ] | - |
dc.description.abstract | The spectroscopic properties and photodimerization reactions of coumarin and 5,7-dimethoxycoumarin in the presence and absence of Lewis acids have been investigated. Coumarin photodimerization quantum yields increased in the presence of $BF_3 \cdot OEt_2$ but those of 5,7-dimethoxycoumarin decreased with small amount of $BF_3\cdot OEt_2$. The enhanced quantum yields for coumarin photodimerization in the presence of $BF_3\cdot OEt_2$ is due to changes of spectroscopic and photophysical properties. UV absorbance of coumarin increased and fluorescence emission intensity is greatly increased with increasing $BF_3\cdot OEt_2$ concentration. Enhanced fluorescence emission intensity is due to a weakening of the vibronic interaction between the $^1(n,\pi^*)$ and $^1(\pi,\pi^*)$ state, as the $^1(n, \pi^*)$ state is raised in energy by $BF_3\cdot OEt_2$ complexation. Consequently, the excited $^1(\pi,\pi^* )$ of coumarin-$BF_3\cdot OEt_2$ complex will be kinetically and electronically more reactive than coumarin alone. In distinction from coumarin, 5,7-dimethoxycoumarin photodimerization quantum yields decreased in spite of increasing fluorescence emission intensity and UV absorbance at 366 nm in the presence of $BF_3\cdot OEt_3 \cdot BF_3 \cdot OEt_2$ inhibits the 5,7-dimethoxycoumarin photodimerization reaction because 5,7-dimethoxycoumarin-$BF_3\cdot OEt_2$ complex absorbs light more strongly but 3,4-double bond character is greatly decreased by $BF_3\cdot OEt_2$ complexation and charge transfer from 5,7-methoxy groups. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Lewis acid catalysis of Coumarin and 5,7-Dimethoxycoumarin photodimerization | - |
dc.title.alternative | 쿠마린과 5,7-디메톡시쿠마린의 광이합체화 반응에 대한 루이스산 효과 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 65512/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000851071 | - |
dc.contributor.localauthor | Shim, Sang-Chul | - |
dc.contributor.localauthor | 심상철 | - |
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