DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Jung, Kyung-Hoon | - |
dc.contributor.advisor | 정경훈 | - |
dc.contributor.author | Jung, Kwang-Woo | - |
dc.contributor.author | 정광우 | - |
dc.date.accessioned | 2011-12-13T04:56:26Z | - |
dc.date.available | 2011-12-13T04:56:26Z | - |
dc.date.issued | 1985 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=64399&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32433 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1985.2, [ ix, 57 p. ] | - |
dc.description.abstract | The competitive phtochlorination reactions were studied for $SiHCl_3/C_2H_6$ and $SiH_2Cl_2/C_2H_6$ systems to elucidate the kinetic parameters of hydrogen abstractions from silanes. The expression of rate constant ratio for the product formation was found to be ◁수식 삽입▷(원문을 참조하세요) Where $ α=[C_2H_5Cl]/[RCl], β=[C_2H_6]_o/[RH]_o$ and $ γ=[RCl]/[RH]_o$. The general mechanism to deduce the equation was proposed ◁수식 삽입▷(원문을 참조하세요) Kinetic data were obtained utilizing the observed $k_1/k_1``$ values at various temperature. Combining the Arrhenius parameters from the known value of the absolute rate constant of ethane we obtained ◁수식 삽입▷(원문을 참조하세요) The anomalous behavior of silanes with respect to carbon counterparts were interpreted in terms of electronic effects and of the structural differences between these compounds. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Competitive photochlorination reactions of silanes at 337.1 nm | - |
dc.title.alternative | 실란의 337.1 nm 파장에서의 광 염소화 경쟁반응 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 64399/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000831633 | - |
dc.contributor.localauthor | Jung, Kyung-Hoon | - |
dc.contributor.localauthor | 정경훈 | - |
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