DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Oh, Dong-Young | - |
dc.contributor.advisor | 오동영 | - |
dc.contributor.author | Moon, Surk-Sik | - |
dc.contributor.author | 문석식 | - |
dc.date.accessioned | 2011-12-13T04:54:41Z | - |
dc.date.available | 2011-12-13T04:54:41Z | - |
dc.date.issued | 1982 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=63264&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32314 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1982.2, [ iii, 48 p. ] | - |
dc.description.abstract | Imine was prepared by the reaction of 2,6-diethylaniline with an excess paraformaldehyde, generated water being removed effectively with water determination apparatus. The protons of $N=CH_2$ in the imine exhibited a second-order spectrum. The imine reacted with bifuntional chloride to give N-(choromethyl)-N-(2,6-diethylphenyl)-carbamoylsulfenyl chloride. The reaction of the carbamolsulfenyl chloride with various equimolar alcohols resulted in the formation of the carbamoyl-sulfenate esters in 71-95\% yields. The corresponding carbamoyl-sulfenate esters decomposed gradually, but the thermal rearrangement of S-O bonding S=O bonding was not found. The nucleophilic attack of an exess alcohol to the carbamoylsulfenyl chloride was made on both divalent sulfur and $\alpha$-carbon of N-chloromethyl group. The corresponding substituted products were considerably stable to light. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Synthesis of carbamoylsulfenyl chloride and its derivatives | - |
dc.title.alternative | 카바모일술페닐 클로라이드와 그 유도체의 합성 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 63264/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000801090 | - |
dc.contributor.localauthor | Oh, Dong-Young | - |
dc.contributor.localauthor | 오동영 | - |
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