DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Oh, Dong-Young | - |
dc.contributor.advisor | 오동영 | - |
dc.contributor.author | Kim, Byeong-Hyo | - |
dc.contributor.author | 김병효 | - |
dc.date.accessioned | 2011-12-13T04:54:36Z | - |
dc.date.available | 2011-12-13T04:54:36Z | - |
dc.date.issued | 1982 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=63258&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32308 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1982.2, [ ii, 50 p. ] | - |
dc.description.abstract | Syntheses of several new tetravalent phosphorus-containing heterocycles from isopropylphosphonic dichloride and from isopropylphosphonothioic dichloride are investigated. Isopropylphosphonic dichloride is prepared by the aluminum chloride method (Kinnear-Perren reaction). Isopropylphosphonothioic dichloride is obtained by the high-temperature reaction of phosphorus pentasulfide with isopropylphosphonic dichloride. These compounds are then esterified with ethylene glycol, mercaptoethanol, ethanedithiol, 2,3-buthanediol, propylene glycol, 2-phenyl-1,2-ethanediol, and 1,3-buthanediol, related phosphorus-containing heterocycle. Triethylamine is used as the hydrochloric acid trapping agent. The structure of phospholanes and phosphorinanes are characterized by its IR, $^1H$ NMR, elemental analysis, and mass spectrometry. It is recognized that the electron impact mass spectrometry is a useful method for the characterization of phosphorus-containing heterocycles. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Synthesis and characterization of phosphorus-containing heterocycles | - |
dc.title.alternative | 인을 내포한 헤테로고리 화합물의 합성 및 분석 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 63258/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000801039 | - |
dc.contributor.localauthor | Oh, Dong-Young | - |
dc.contributor.localauthor | 오동영 | - |
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