A condenser air removal system plays a crucial role in radiation monitoring within nuclear power plants, specifically for detecting potential leaks of radioactive material from primary-to-secondary systems. This system assesses the leakage rate (LR) by measuring the emission of (3 particles from noble gases using a thin plastic scintillation (TPS) detector, which is specifically designed for counting purposes. Among the factors used in LR calculation, the detection efficiency (k) k ) must be experimentally determined in advance. However, this is challenging because of the limitations posed by radiation safety regulations. Moreover, simulation-based calculations are difficult to achieve because only a portion of the (3-ray energy is transferred in the TPS detectors, resulting in a lack of prior energy information. To overcome these challenges, this study employed a multi-objective parameter optimization technique to simultaneously calculate the parameters required for the (3-ray detection response function and energy calibration equation. Subsequently, k values were calculated using the optimization results. The optimization performance was demonstrated by comparing the measured spectra of the TPS detector with the spectra obtained from the Monte Carlo N-particle simulation. Furthermore, we confirmed that the calculated k values agreed with the reference values.