DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Chang, Suk-bok | - |
dc.contributor.advisor | 장석복 | - |
dc.contributor.author | Kim, Seok-Hwan | - |
dc.contributor.author | 김석환 | - |
dc.date.accessioned | 2011-12-13T04:50:58Z | - |
dc.date.available | 2011-12-13T04:50:58Z | - |
dc.date.issued | 2008 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=297288&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32065 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 2008.2, [ iii, 57 p. ] | - |
dc.description.abstract | Recently our group developed three-component coupling reaction of sulfonyl azide, alkyne and nucleophilic reaction partners such as amine, alcohol and water. We found that phosphoryl azide can also be used in this type of reaction affording corresponding amidines with good to excellent yields. Phosphoryl azide has more structural diversity than sulfonyl azides, to give more potential, practical application by changing the alcohol moiety. The introduction of BINOL (1,1’-Bi-2-naphthol), a typical chiral auxiliary into the amidine structure engendered an asymmetric environment on α-position of the amidine. This chiral amidine underwent successful asymmetric alkylation reactions with methyl, benzyl and allyl groups. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | Phosphoryl azide | - |
dc.subject | Phosphoryl amidine | - |
dc.subject | 포스포릴 아지드 | - |
dc.subject | 포스포릴 아미딘 | - |
dc.subject | Phosphoryl azide | - |
dc.subject | Phosphoryl amidine | - |
dc.subject | 포스포릴 아지드 | - |
dc.subject | 포스포릴 아미딘 | - |
dc.title | Phosphoryl amidine synthesis using phosphoryl azides under the Cu-catalyzed three-component couplings | - |
dc.title.alternative | 포스포릴 아지드를 사용한 구리촉매 삼성분 짝지움 반응 하에서의 포스포릴 아미딘 합성 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 297288/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 020063070 | - |
dc.contributor.localauthor | Chang, Suk-bok | - |
dc.contributor.localauthor | 장석복 | - |
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